Light energy conversion device for photocatalyst 2.0%WO3-TiO2 withoxygen vacancies for water splitting
来源期刊：中南大学学报(英文版)2010年第5期
论文作者：童海霞 陈启元 胡慧萍 尹周澜
文章页码：943 - 946
Key words：light energy conversion device; photocatalytic activity; O2 evolution; oxygen vacancy; photo splitting water
Abstract: Using carbon felt, polytetrafluoroethylene latex and powder catalyst to assembly a light energy conversion device, the photocatalytic activity of catalyst 2.0%WO3-TiO2 (2%WO3 compounding TiO2) with oxygen vacancies was studied through the water splitting for O2 evolution, using a high pressure mercury lamp as the light source and Fe3+ as the electron acceptor in two different devices: an ordinary photolysis device with catalyst powder suspending through a magnetic stirrer and a self-assembly light energy conversion device. The results show that after 12 h irradiation, the photocatalytic activity of 2.0%WO3-TiO2 with oxygen vacancies in the self-assembly light energy conversion device is higher than that of the ordinary photolysis device, and the amount of oxygen evolution is about 12 and 9 mmol/L respectively in these two devices. After 12 h, the rates of O2 evolution are slow in each device and the photocatalyst almost loses the photoactivity in the ordinary photolysis device. So, compared with the ordinary photocatalytic device, the rate of oxygen evolution and the life time of the catalyst are improved in the self-assembly light energy conversion device.
