Electrodeposition of Ni-SiC nanocomposite film
来源期刊:中国有色金属学报(英文版)2007年第1期
论文作者:牛朝霞 曹发和 王玮 张昭 张鉴清 曹楚南
文章页码:9 - 15
Key words:Ni-SiC nanocomposite film; point of zero charge; potentiometric titration; electroplating
Abstract: The point of zero charge(PZC) of SiC nanoparticles was determined by means of standard potentiometric titration method, while the influences of the main technological parameters on the microstructure of electrodeposited Ni-SiC composite film were studied and optimized. The results show that high bath pH value favors SiC nanoparticles negatively charged and high bath temperature promotes them positively charged. Under the experimental conditions, sodium dodecyl-glycol is proven to be an effective surface modification anionic surfactant for SiC nanoparticles. The results also show that the optimized Ni-SiC composite film is composed of the nanoparticles with the average grain size in the nanometer range (100 nm), and SiC nanoparticles disperse into the nickel matrix uniformly.
基金信息:by the National Natural Science Foundation of China