Structure and electrochemical properties of Li(Ni_0.5Mn_0.5)_1-xTi_xO₂ prepared by one-step solid state reaction

来源期刊：中国有色金属学报(英文版)2006年第6期

论文作者：曹四海 王志兴 李新海 郭华军 彭文杰 尹周澜

文章页码：1247 - 1251

Key words：Li-ion battery; cathode; LiNi_0.5Mn_0.5O₂; doping; Ti; cyclic voltammetry

Abstract: The layered compound Li(Ni_0.5Mn_0.5)_1-xTi_xO₂ powders were prepared with Ni(OH)₂, MnCO₃, Li₂CO₃ and TiO₂ by one-step solid state reaction. The effect of doping Ti on the structure and electrochemical properties was studied. The XRD results indicate that the powders with 0≤x≤0.05 have good layered structure and trace of impurity appears in the samples with x≥0.1. The SEM photographs show that the particle size distributes homogeneously and the sample with x=0.15 has larger particle size than other samples. The charge-discharge tests show that Li(Ni_0.5Mn_0.5)_0.95Ti_0.05O₂ synthesized at 800 ℃ for 36 h exhibits good electrochemical properties. It firstly delivers 173 mA·h/g and maintains 90% of the initial discharge capacity after 30 cycles. The cyclic voltammetry and differential capacity vs voltage curves show that the major oxidation and reduction peaks are around 3.95 V and 3.75 V, respectively, assigned to Ni²⁺/Ni⁴⁺ oxidation-reduction process. A weak peak around 4.5 V is found during the oxidation process in the first cycle, which can be regarded as the main reason of the large drop of discharge capacity in the initial cycle.