Preparation and characterization of nanometer-sized barium titanate powder by complex-precursor method
来源期刊:中南大学学报(英文版)2008年第3期
论文作者:石爱华 颜文斌 李佑稷 黄可龙
文章页码:334 - 338
Key words:barium titanate; complex-precursor method; synthesis; nanometer-sized powder
Abstract: A new complex-precursor method was proposed to prepare nanometer-sized BaTiO3 powder. Firstly, [Ti2O(O2)2(ta)2]4- complex ions were prepared by the reaction of H2O2, Ti4+ and ta3- (ta=[C6H6O6N]3-) with a desirable amount of surface active agent, and then the Ba2[Ti2O(O2)2(ta)2]·2H2O precursor was obtained by reaction between [Ti2O(O2)2(ta)2]4- and Ba2+. Finally, the precursor was annealed at 800 ℃ for 2 h to obtain BaTiO3 powder. The morphology, the particle size distribution, the purity and the molar ratio of Ba to Ti of BaTiO3 powder were investigated systematically by TEM, XRD, IR, Raman and chemical analysis, respectively. The results show that the BaTiO3 powders with the grain size of about 40 nm have a tetragonal crystalline structure at room temperature and a spherical morphology.
基金信息:the Hunan Provincial Natural Science Foundation of China