Dependence of Magnetic Properties of Rapidly Quenching (Nd,Pr)x(FeCoZr)94-xB6 Bonded Magnets on Rare Earths Content
来源期刊:JOURNAL OF RARE EARTHS2004年第3期
论文作者:查五生 连利仙 涂铭旌 高升吉 刘颖
Key words:metal materials; Pr-based permanent magnets; nanocrystalline composite; magnetic properties; completely coupling model; rare earths;
Abstract: By using sub-overquenching and annealing method which has a wide processing window, (Nd, Pr)x(FeCoZr)94-xB6 (x=12, 10.5, 10, 9) bonded magnets were prepared and the effect of rare earths content on magnetic properties was investigated. Being spun at sub-overquenching speed the as-spun ribbons consist of amorphous phases mixed with fine crystallites. After crystallization under optimum annealing conditions and bonded with 3.25% (mass fraction) epoxy, the magnets obtained the optimum magnetic properties. The rare earths content directly determines the magnetic properties. With the reduction of rare earths content, Br increases but Hci and (BH)max decrease. x=10 is the critical value for the magnetic properties change. Below this value, Br increases slowly meanwhile Hci and (BH)max decrease strongly because alloy contains extra fractions of soft magnetic phase which are not coupled with the hard magnetic phase. This experimental result is consistent with the calculated results using the model of volume fraction of soft magnetic phase coupled completely suggested.
查五生1,连利仙1,涂铭旌1,高升吉1,刘颖1
(1.College of Material Science & Engineering, Sichuan University, Chengdu 610065, China;
2.College of Material Science & Engineering, Xihua University, Chengdu 610039, China)
Abstract:By using sub-overquenching and annealing method which has a wide processing window, (Nd, Pr)x(FeCoZr)94-xB6 (x=12, 10.5, 10, 9) bonded magnets were prepared and the effect of rare earths content on magnetic properties was investigated. Being spun at sub-overquenching speed the as-spun ribbons consist of amorphous phases mixed with fine crystallites. After crystallization under optimum annealing conditions and bonded with 3.25% (mass fraction) epoxy, the magnets obtained the optimum magnetic properties. The rare earths content directly determines the magnetic properties. With the reduction of rare earths content, Br increases but Hci and (BH)max decrease. x=10 is the critical value for the magnetic properties change. Below this value, Br increases slowly meanwhile Hci and (BH)max decrease strongly because alloy contains extra fractions of soft magnetic phase which are not coupled with the hard magnetic phase. This experimental result is consistent with the calculated results using the model of volume fraction of soft magnetic phase coupled completely suggested.
Key words:metal materials; Pr-based permanent magnets; nanocrystalline composite; magnetic properties; completely coupling model; rare earths;
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