Effect of KNbO3 content on the crystal structure and electrical properties of(1-x)PbZr0.54Ti0.46O3-xKNbO3 piezoelectric ceramics
来源期刊:International Journal of Minerals Metallurgy and Materials2013年第3期
论文作者:Lei Zhao Bo-ping Zhang Min Cui Yan Li
文章页码:279 - 283
摘 要:(1-x)PbZr0.54Ti0.46 O3-xKNbO3 (0 ≤ x ≤ 25mol%) (abbreviated as PZT-xKN) piezoelectric ceramics were successfully fabricated by a traditional sintering technique at 1225℃ for 30 min. The influence of KNbO3 content on the crystal structure and electrical properties of the PZT-xKN piezoelectric ceramics was studied. Samples with 0 ≤ x ≤ 0.20 show a pure perovskite structure, indicating that all KNbO3 diffused into the crystal lattice of PZT to form a single solid solution in this compositional range. A second Pb3Nb4O13 phase is observed in the PZT-0.25KN sample, showing that the maximum solid solubility of KNbO3 in PZT matrix ceramic is less than 25mol%. Compared with pure PZT piezoelectric ceramics, samples containing KNbO3 have smaller crystal grains. PZT-0.15KN exhibits excellent piezoelectric properties with d33 = 209 pC/N.
Lei Zhao,Bo-ping Zhang,Min Cui,Yan Li
School of Materials Science and Engineering, University of Science and Technology Beijing
摘 要:(1-x)PbZr0.54Ti0.46 O3-xKNbO3 (0 ≤ x ≤ 25mol%) (abbreviated as PZT-xKN) piezoelectric ceramics were successfully fabricated by a traditional sintering technique at 1225℃ for 30 min. The influence of KNbO3 content on the crystal structure and electrical properties of the PZT-xKN piezoelectric ceramics was studied. Samples with 0 ≤ x ≤ 0.20 show a pure perovskite structure, indicating that all KNbO3 diffused into the crystal lattice of PZT to form a single solid solution in this compositional range. A second Pb3Nb4O13 phase is observed in the PZT-0.25KN sample, showing that the maximum solid solubility of KNbO3 in PZT matrix ceramic is less than 25mol%. Compared with pure PZT piezoelectric ceramics, samples containing KNbO3 have smaller crystal grains. PZT-0.15KN exhibits excellent piezoelectric properties with d33 = 209 pC/N.
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