Cu2(ASA)4 配合物的电子光谱
来源期刊：中国有色金属学报1997年第1期
论文作者：刘伟平 熊惠周 杨一昆 谌喜珠 陈植和 沈志强 李玲
文章页码：49 - 51
关键词：乙酰水杨酸 铜配合物 电子光谱
Key words：acetylsalicylate copper(Ⅱ) complex electronic spectrum
摘 要：采用紫外/可见分光光谱法,结合其他分析技术，研究了 tetrakis-[μ-acetylsalicylato-O1O2]dicopper(Ⅱ)(简称Cu2(ASA)4)配合物的电子光谱。实验结果表明，该配合物有三种类型特征吸收谱带，分别归属为2Eg→2T2gd-d 电子跃迁，Cu→Cu d-d 电子迁移和RCOO→Cu的电荷转移。
Abstract: The spectra of tetrakis-[μ-acetylsalicylato-O1O2] dicopper(Ⅱ) complex were studied by using ultra-visible spectrum , combined with other analytical techniques. The results showed that the complex has three kinds of absorption bands, which are 2Eg→2T2gd-d transition, Cu→Cu d-d shift and RCOO→Cu charge transfer.
