The Impact of Nickel Source/Doping Elements/Buffer on the Structure of Ni(OH)2
来源期刊:Journal Of Wuhan University Of Technology Materials Science Edition2014年第1期
论文作者:许庆胜 朱燕娟 HAN Quanyong LUO Jie MIAO Chengcheng ZHANG Wei ZHANG Chunhua
文章页码:44 - 48
摘 要:The nano-nickel hydroxide samples were prepared by means of ultrasonic-assisted precipitation and the impact of source/doping element/buffer on the structure of Ni(OH)2 was studied. The results of XRD, IR and TEM testing clearly revealed that larger anionic radius of the nickel sources or the buffer solution was conducive to the formation of α-Ni(OH)2. The proportion of α-Ni(OH)2 samples doped with two elements was larger than that doped with single element. Additionally, speciation, valence as well as the radius of doping ions can directly affect the phase of Ni(OH)2.
许庆胜,朱燕娟,HAN Quanyong,LUO Jie,MIAO Chengcheng,ZHANG Wei,ZHANG Chunhua
School of Physics and Optoelectronic Engineering, Guangdong University of Technology
摘 要:The nano-nickel hydroxide samples were prepared by means of ultrasonic-assisted precipitation and the impact of source/doping element/buffer on the structure of Ni(OH)2 was studied. The results of XRD, IR and TEM testing clearly revealed that larger anionic radius of the nickel sources or the buffer solution was conducive to the formation of α-Ni(OH)2. The proportion of α-Ni(OH)2 samples doped with two elements was larger than that doped with single element. Additionally, speciation, valence as well as the radius of doping ions can directly affect the phase of Ni(OH)2.
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