Formation and crystallization of Zr-Ni-Ti metallic glass

来源期刊：中国有色金属学报(英文版)2004年第5期

论文作者：刘雄军 惠希东 焦建廷 陈国良

文章页码：858 - 863

Key words：metallic glass; glass forming ability; crystallization; structural transformation; Zr-Ni-Ti

Abstract: The metallic Zr₆₅Ni₂₅Ti₁₀(mole fraction, %) glass has been fabricated by a single roller melt-spinning method. The glass forming ability(GFA) and thermal stability of the Zr₆₅Ni₂₅Ti₁₀ melt-spun ribbons were investigated by using X-ray diffraction(XRD) and differential scanning calorimetry(DSC) in the mode of continuous heating. It is shown that the reduced glass transition temperature (T_rg) is 0.506 and the supercooled liquid region (ΔT_x) is 30 K. Two exothermic peaks were observed in the DSC curves of the as-quenched ribbon, which indicates that the crystallization process undergoes two different stages. The phase transformation during the isothermal annealing was investigated by X-ray diffraction(XRD) and transmission electronic microscope(TEM). It is observed that the metastable FCC Zr₂Ni(Fd3m, a=12.27 A) precipitated while annealing in the suppercooled region(615 K) and the stable BCT Zr₂Ni(I4/mcm, a=6.499 A, c=5.270 A) precipitated while annealing at higher temperature(673 K or 723 K). The crystallines are on nanoscale, with grain size of 15-30 nm. The reason for the precipitation of the different structural Zr₂Ni from the glassy matrix under different annealing conditions was discussed based on the concept of multi-component chemical short range order(MCSRO).