THERMODYNAMIC AND STRUCTURAL CHEMISTRY DISCUSSIONS FOR OXIDATIVE LEACHING OF Cu-Ni SULPHIDE ORE UNDER ATMOSPHERIC PRESSURE
来源期刊:中国有色金属学报(英文版)1995年第3期
论文作者:Wu, Wenjian Chen, Zhong Yang, Songqing Jiang, Hanying
文章页码:29 - 33
Key words:Cu-Ni sulphide ore; leach; ferric chloride; nitric acid
Abstract: HNO3 was calculated to have much more larger thermodynamical tendency to oxidate copper, nickel and iron sulphides than FeCI3. The frontline orbits theory also confirmed that NO3 ̄- reacted with nickel and iron sulphides more easily than Fes3+ . The results of leaching Cu-Ni sulphide ore with FeCI3 and HNO3 were theoretically interpreted.