La2Zr2O7 TBCs toughened by Pt particles prepared by cathode plasma electrolytic deposition
来源期刊:International Journal of Minerals Metallurgy and Materials2016年第6期
论文作者:Shun-jie Deng Peng Wang Ye-dong He Jin Zhang
文章页码:704 - 715
摘 要:La2Zr2O7 thermal barrier coatings(TBCs) with dispersed Pt particles were prepared by cathode plasma electrolytic deposition(CPED) with ceramic balls added to the cathode region. Compared with the conventional CPED, when ceramic balls are used in the cathode region, the plasma discharge ignition current density decreases approximately 62-fold and the stable plasma discharges occur at the whole cathode surface. Such TBCs with a thickness of 100 μm exhibit a crack-free surface and are composed of pyrochlore-structured La2Zr2O7. Cyclic oxidation, scratching, and thermal insulation capability tests show that such TBCs not only exhibit high resistance to oxidation and spallation but also provide good thermal insulation. These beneficial effects are attributed to the excellent properties of TBCs, such as good thermal insulation because of low thermal conductivity, high-temperature oxidation resistance because of low-oxygen diffusion rate, and good mechanical properties because of the toughening effect of Pt particles.
Shun-jie Deng,Peng Wang,Ye-dong He,Jin Zhang
Institute for Advanced Materials and Technology, University of Science and Technology Beijing
摘 要:La2Zr2O7 thermal barrier coatings(TBCs) with dispersed Pt particles were prepared by cathode plasma electrolytic deposition(CPED) with ceramic balls added to the cathode region. Compared with the conventional CPED, when ceramic balls are used in the cathode region, the plasma discharge ignition current density decreases approximately 62-fold and the stable plasma discharges occur at the whole cathode surface. Such TBCs with a thickness of 100 μm exhibit a crack-free surface and are composed of pyrochlore-structured La2Zr2O7. Cyclic oxidation, scratching, and thermal insulation capability tests show that such TBCs not only exhibit high resistance to oxidation and spallation but also provide good thermal insulation. These beneficial effects are attributed to the excellent properties of TBCs, such as good thermal insulation because of low thermal conductivity, high-temperature oxidation resistance because of low-oxygen diffusion rate, and good mechanical properties because of the toughening effect of Pt particles.
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