Polyurethane Grafted Attapulgite as Novel Fillers for Nylon 6 Nanocomposites
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2011年第4期
论文作者：史建设 杨绪杰
文章页码：615 - 619
摘 要：Attapulgite fibers were modified by polyurethane, forming polyurethane grafted attapulgite （AT-PU）, which was confirmed by Fourier transform infrared spectroscopy （FTIR）, X-ray diffraction （XRD） and X-ray photoelectron spectroscopy （XPS）. Nylon 6/AT-PU nanocomposites of different modified attapulgite loadings were prepared by melt blending in a twin screw extruder. Scanning electron microscopy （SEM） observation on the fracture surfaces of the nanocomposites showed not only a uniform dispersion of AT-PU but also a strong interfacial adhesion with the matrix. Differential scanning calorimeter （DSC） and Thermogravimetric analyzer （TGA） were used to illustrate the infiuence of AT-PU particles on the thermal properties of the nylon 6/AT-PU nanocomposites. The results indicated that the addition of attapulgite probably induced the heterogeneous nucleation and was favorable for the formation of γ -crystalline form, and that the higher thermal stability was obtained for the composites.
史建设，杨绪杰
Key Laboratory for Soft Chemistry and Functional Material of the Ministry Education, Nanjing University of Science and Technology
摘 要：Attapulgite fibers were modified by polyurethane, forming polyurethane grafted attapulgite （AT-PU）, which was confirmed by Fourier transform infrared spectroscopy （FTIR）, X-ray diffraction （XRD） and X-ray photoelectron spectroscopy （XPS）. Nylon 6/AT-PU nanocomposites of different modified attapulgite loadings were prepared by melt blending in a twin screw extruder. Scanning electron microscopy （SEM） observation on the fracture surfaces of the nanocomposites showed not only a uniform dispersion of AT-PU but also a strong interfacial adhesion with the matrix. Differential scanning calorimeter （DSC） and Thermogravimetric analyzer （TGA） were used to illustrate the infiuence of AT-PU particles on the thermal properties of the nylon 6/AT-PU nanocomposites. The results indicated that the addition of attapulgite probably induced the heterogeneous nucleation and was favorable for the formation of γ -crystalline form, and that the higher thermal stability was obtained for the composites.
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