关于Cu-Cl-H2O系的热力学分析及电位-pH图
来源期刊:中南大学学报(自然科学版)1980年第3期
论文作者:傅崇说 郑蒂基
文章页码:12 - 24
关键词:分析方法; 临界点; 热力学分析; 氯化亚铜; 络合物;平衡电位;电位-PH图
摘 要:本文根据同时平衡原理对Cu—Cl-—H2O系进行了全面的热力学分析,并在此基础上绘出了这个体系在25℃下的各种电位-pH图。分析方法所包括的基本观点和计算步骤,原则上适用于一切有多种络合物形成的复杂体系,可导出一系列有用的结果,这些结果无论对理论研究或生产实践都具有重要的意义。
Abstract: According to the principle of simultaneous equilibrium a complete thermo-dynamic analysis on the Cu-Cl--H2O system has been made,and on thisbasis its various potential-pH diagrams at 25℃ are constructed.The basicConcepts and steps of calculation involved in the analytical method are appli-cable to all complex systems.From this method a series of data can bederived,and these data are available both in theoretical study and inpractice.