简介概要

Highly thermal-conductive graphite flake/Cu composites prepared by sintering intermittently electroplated core-shell powders

来源期刊:JOURNAL OF MATERIALS SCIENCE TECHNOLOG2021年第2期

论文作者:Hong Sun Nan Deng Jianqiang Li Gang He Jiangtao Li

摘    要:Graphite flake/Cu composite has attracted tremendous attention as a promising heat sinks materials owing to its easy machinability and superior thermal properties. However, its preparation process still faces several technological limitations including complex, time-consuming and costly synthetic approaches. In this work, a facile and scalable intermittently electroplated method is applied to prepare Cu-coated graphite flake composite powders, which are subsequently sintered into dense composite bulks. The results show that the graphite flake is successfully coated with a uniform and compact Cu shell,which effectively inhibits the segregation accumulation of graphite flakes and contributes to homogeneous distribution of graphite in the sintered graphite flake/Cu composites. The as-sintered composites exhibit an excellent thermal conductivity of 710 W·m-1·K-1and an outstanding bending strength of 93 MPa. Such performance, together with the simple, efficient powder-preparation process, suggests that the present strategy may open up opportunities for the development of thermal management materials.

详情信息展示

Highly thermal-conductive graphite flake/Cu composites prepared by sintering intermittently electroplated core-shell powders

Hong Sun1,2,Nan Deng1,3,Jianqiang Li1,2,Gang He4,Jiangtao Li4

1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences2. University of Chinese Academy of Sciences3. School of Materials Science and Engineering, University of Science and Technology Beijing4. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences

摘 要:Graphite flake/Cu composite has attracted tremendous attention as a promising heat sinks materials owing to its easy machinability and superior thermal properties. However, its preparation process still faces several technological limitations including complex, time-consuming and costly synthetic approaches. In this work, a facile and scalable intermittently electroplated method is applied to prepare Cu-coated graphite flake composite powders, which are subsequently sintered into dense composite bulks. The results show that the graphite flake is successfully coated with a uniform and compact Cu shell,which effectively inhibits the segregation accumulation of graphite flakes and contributes to homogeneous distribution of graphite in the sintered graphite flake/Cu composites. The as-sintered composites exhibit an excellent thermal conductivity of 710 W·m-1·K-1and an outstanding bending strength of 93 MPa. Such performance, together with the simple, efficient powder-preparation process, suggests that the present strategy may open up opportunities for the development of thermal management materials.

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