Promising light converting BaMoO4:Er3+-Tm3+-Yb3+ phosphors for display and optical temperature sensing
来源期刊：Journal of Rare Earths2018年第12期
论文作者：Abhishek Kumar Soni Vineet Kumar Rai
文章页码：1256 - 1263
摘 要：Er3+-Tm3+-Yb3+ tri-doped BaMoO4 phosphors were synthesized by co-precipitation technique and characterized by X-ray diffraction analysis, absorption study and field emission scanning electron microscopy analysis. Upconversion as well as downconversion luminescence studies were performed by using near infrared（980 nm） and ultraviolet（380 nm） excitations. Energy level diagram, pump power dependence and colour coordinate study were utilized to describe the multicolor upconversion emission properties. Under single 980 nm diode laser excitation the dual mode sensing behaviour is realized via Stark sublevels and thermally coupled energy levels of the Tm3+ and Er3+ ions in the prepared tri-doped phosphors. A comparative fluorescence intensity ratio analysis for integrated emission intensities arising from the Stark sublevels {1 G4（a） and 1 G4（b）} and thermally coupled energy levels {2 H11/2 and 4 S3/2} of the Tm3+ and Er3+ ions, respectively was carried out in the prepared tri-doped BaMoO4 phosphors. The maximum sensitivity for thermally coupled energy levels of the Er3+ and Stark sublevels of the Tm3+ ion was reported. The developed phosphors could be useful in the display devices and optical thermo metric applications.
Abhishek Kumar Soni1，Vineet Kumar Rai2
1. Chemistry Division, Bhabha Atomic Research Centre2. Laser and Spectroscopy Laboratory,Department of Applied Physics, Indian Institute of Technology (Indian School of Mines)
摘 要：Er3+-Tm3+-Yb3+ tri-doped BaMoO4 phosphors were synthesized by co-precipitation technique and characterized by X-ray diffraction analysis, absorption study and field emission scanning electron microscopy analysis. Upconversion as well as downconversion luminescence studies were performed by using near infrared（980 nm） and ultraviolet（380 nm） excitations. Energy level diagram, pump power dependence and colour coordinate study were utilized to describe the multicolor upconversion emission properties. Under single 980 nm diode laser excitation the dual mode sensing behaviour is realized via Stark sublevels and thermally coupled energy levels of the Tm3+ and Er3+ ions in the prepared tri-doped phosphors. A comparative fluorescence intensity ratio analysis for integrated emission intensities arising from the Stark sublevels {1 G4（a） and 1 G4（b）} and thermally coupled energy levels {2 H11/2 and 4 S3/2} of the Tm3+ and Er3+ ions, respectively was carried out in the prepared tri-doped BaMoO4 phosphors. The maximum sensitivity for thermally coupled energy levels of the Er3+ and Stark sublevels of the Tm3+ ion was reported. The developed phosphors could be useful in the display devices and optical thermo metric applications.
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