Spectroscopic Properties of Er3+-Doped TeO2-WO3-ZnO-ZnF2 Glasses
来源期刊:JOURNAL OF RARE EARTHS2004年第3期
论文作者:干福熹 胡和方 李顺光 李家成
Key words:optics; spectroscopic properties; Er3+-doping; tungsten-tellurite glasses; emission bandwidth; rare earths;
Abstract: The Er3+-doped TeO2-WO3-ZnO-ZnF2(TWZOF) glasses were prepared. The absorption spectra, 1.5 μm emission spectra and fluorescence lifetimes of Er3+, excited at 970 nm, were measured. The J-O parameters Ωt (t=2, 4, 6), absorption and emission cross-sections were calculated. The dependence of the 1.5 μm emission intensity, fluorescence lifetime and bandwidth of the Er3+ emission upon the contents of ZnF2 in glass were investigated. In TWZOF glass, Er3+ ions had a broad emission profile around 1.5 μm with the maximum FWHM of 83 nm. With the increasing of the content of ZnF2, the emission intensity at peak wavelength and the fluorescence lifetime of Er3+ at 1.5 μm increase.
干福熹1,胡和方1,李顺光1,李家成1
(1.Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China;
2.Graduate School of the Chinese Academy of Sciences, Beijing 100039, China)
Abstract:The Er3+-doped TeO2-WO3-ZnO-ZnF2(TWZOF) glasses were prepared. The absorption spectra, 1.5 μm emission spectra and fluorescence lifetimes of Er3+, excited at 970 nm, were measured. The J-O parameters Ωt (t=2, 4, 6), absorption and emission cross-sections were calculated. The dependence of the 1.5 μm emission intensity, fluorescence lifetime and bandwidth of the Er3+ emission upon the contents of ZnF2 in glass were investigated. In TWZOF glass, Er3+ ions had a broad emission profile around 1.5 μm with the maximum FWHM of 83 nm. With the increasing of the content of ZnF2, the emission intensity at peak wavelength and the fluorescence lifetime of Er3+ at 1.5 μm increase.
Key words:optics; spectroscopic properties; Er3+-doping; tungsten-tellurite glasses; emission bandwidth; rare earths;
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