Thermoelectric properties of Yb x Co4 Sb12 system
来源期刊：Journal of Rare Earths2012年第5期
论文作者：刘洪权 赵新兵 朱铁军 谷亦杰
文章页码：456 - 459
摘 要：Yb x Co 4 Sb 12 polycrystals were fabricated by vacuum melting combined with hot-press sintering.The effect of Yb-filling on thermoelectric property of unfilled skutterudite CoSb 3 was investigated,which indicated the enhancement of the power factor of the material.Transport properties of materials changed from semi-conductor to semi-metal during the measurement of electrical conductivity,which indicated the change of electronic band structure.The maximum value of electrical conductivity was about 190000 S/m at 300 K for all samples.On the basis of Yb-filling,power factor of Yb 0.2 Co 4 Sb 12 reached 5-6 mW/（m·K） during the measurement temperature.Thermal conductivity decreased with increase of Yb content,and the thermal conductivity of Yb 0.2 Co 4 Sb 12 reached 3.2 W/（m·K） at 600 K.The ZT value of Yb 0.2 Co 4 Sb 12 reached 1.16 at 700 K due to positive contribution from high power factor and low thermal conductivity.
刘洪权1，赵新兵2，朱铁军2，谷亦杰1
1. College of Materials Science and Engineering,Shandong University of Science and Technology2. Department of Materials Science,State Key Laboratory of Silicon Materials,Zhejiang University
摘 要：Yb x Co 4 Sb 12 polycrystals were fabricated by vacuum melting combined with hot-press sintering.The effect of Yb-filling on thermoelectric property of unfilled skutterudite CoSb 3 was investigated,which indicated the enhancement of the power factor of the material.Transport properties of materials changed from semi-conductor to semi-metal during the measurement of electrical conductivity,which indicated the change of electronic band structure.The maximum value of electrical conductivity was about 190000 S/m at 300 K for all samples.On the basis of Yb-filling,power factor of Yb 0.2 Co 4 Sb 12 reached 5-6 mW/（m·K） during the measurement temperature.Thermal conductivity decreased with increase of Yb content,and the thermal conductivity of Yb 0.2 Co 4 Sb 12 reached 3.2 W/（m·K） at 600 K.The ZT value of Yb 0.2 Co 4 Sb 12 reached 1.16 at 700 K due to positive contribution from high power factor and low thermal conductivity.
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