Study on Luminescence Properties of High-Density Phosphors BiTaO4∶Pr3+ and BiTaO4
来源期刊：JOURNAL OF RARE EARTHS2003年第2期
论文作者：刘波 郭常新 施朝淑 张庆礼
Key words：optics; rare earths; BiTaO4∶Pr3+; BiTaO4; luminescence;
Abstract: The photoluminescence properties of BiTaO4∶Pr3+ and BiTaO4 at room temperature were studied, and the infrared transmission and diffusion reflection spectra of BiTaO4 were measured. The photoluminescence spectrum of BiTaO4 peaks at about 420, 440 and 465 nm. There has an obvious excitation band from 330 to 370 nm. The photoluminescence spectrum of BiTaO4∶Pr3+ consists of the characteristic emission of Pr3+, and its main peak is at 606 nm from 3P0→3H6 transition of Pr3+. Its excitation spectrum consists of the wide band with maximum at 325 nm, the wide band in the range of 375～430 nm, and the characteristic excitation of Pr3+. The bands at 325 nm and 375～430 nm may be from the absorption of the charge transfer transition of the tantalate group and defect energy levels in its forbidden band, respectively. There is energy transfer from host to Pr3+. Because both the host density and photoluminescence peak intensity of BiTaO4∶Pr3+ are superior to PbWO4, BiTaO4∶Pr3+ may be a potential heavy scintillator.
刘波1，郭常新1，施朝淑1，张庆礼2
(1.Department of Physics of University of Science and Technology of China, Hefei 230026, China;
2.Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China)
Abstract:The photoluminescence properties of BiTaO4∶Pr3+ and BiTaO4 at room temperature were studied, and the infrared transmission and diffusion reflection spectra of BiTaO4 were measured. The photoluminescence spectrum of BiTaO4 peaks at about 420, 440 and 465 nm. There has an obvious excitation band from 330 to 370 nm. The photoluminescence spectrum of BiTaO4∶Pr3+ consists of the characteristic emission of Pr3+, and its main peak is at 606 nm from 3P0→3H6 transition of Pr3+. Its excitation spectrum consists of the wide band with maximum at 325 nm, the wide band in the range of 375～430 nm, and the characteristic excitation of Pr3+. The bands at 325 nm and 375～430 nm may be from the absorption of the charge transfer transition of the tantalate group and defect energy levels in its forbidden band, respectively. There is energy transfer from host to Pr3+. Because both the host density and photoluminescence peak intensity of BiTaO4∶Pr3+ are superior to PbWO4, BiTaO4∶Pr3+ may be a potential heavy scintillator.
Key words:optics; rare earths; BiTaO4∶Pr3+; BiTaO4; luminescence;
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