Investigation on the syntheses and structures of YⅢ complexes with ami-nopolycarboxylic acids （Ⅳ）
来源期刊：Rare Metals2002年第2期
论文作者：WANG Jun, ZHANG Xiangdong, LING Xiao, JIA Weiguo, and FAN DaminDepartment of Chemistry, Liaoning University, Shenyang, , China
文章页码：106 - 112
摘 要：<正>This paper deals with the structure of the YIII complex with aminopolycarboxylic acids, synthesis and structural determination of the complex （NH4）[YIII（edta）（H2O）3]·3H2O （edta = ethylenediaminetetraacetic acid）. The crystal and molecular structures of the （NH4）[YIII（edta）（H2O）3]·3H2O complex have been determined by single-crystal X-ray structure analysis. The crystal of the complex （NH4）[YIII（edta）（H2O）3]·3H2O belongs to orthorhombic crystal system and fdd2 space group. The crystal data are as follows: a=1.944 1（9） nm, b= 3.545 9（18） nm, c = 1.219 6（6） nm, V= 8.407 （7）nm3,Z=16, Mr= 503.25, Dc= 1.590g.cm3, μ= 2.844 mm 1 and F（000） = 4 160. The final R and Ru are 0.048 6 and 0.133 2 for 3 388 （I>2σ（I）） unique reflections, respectively. The complex anion [YIII（edta）（H2O）3] has a pseudo-mono-capped square antiprismatic nine-coordinate structure in which the six coordinate atoms （two N and four O） are from an edta ligand and three water molecules coordinate to the central YIII ion directly. From the res
WANG Jun, ZHANG Xiangdong, LING Xiao, JIA Weiguo, and FAN DaminDepartment of Chemistry, Liaoning University, Shenyang, 110036, China
摘 要：<正>This paper deals with the structure of the YIII complex with aminopolycarboxylic acids, synthesis and structural determination of the complex （NH4）[YIII（edta）（H2O）3]·3H2O （edta = ethylenediaminetetraacetic acid）. The crystal and molecular structures of the （NH4）[YIII（edta）（H2O）3]·3H2O complex have been determined by single-crystal X-ray structure analysis. The crystal of the complex （NH4）[YIII（edta）（H2O）3]·3H2O belongs to orthorhombic crystal system and fdd2 space group. The crystal data are as follows: a=1.944 1（9） nm, b= 3.545 9（18） nm, c = 1.219 6（6） nm, V= 8.407 （7）nm3,Z=16, Mr= 503.25, Dc= 1.590g.cm3, μ= 2.844 mm 1 and F（000） = 4 160. The final R and Ru are 0.048 6 and 0.133 2 for 3 388 （I>2σ（I）） unique reflections, respectively. The complex anion [YIII（edta）（H2O）3] has a pseudo-mono-capped square antiprismatic nine-coordinate structure in which the six coordinate atoms （two N and four O） are from an edta ligand and three water molecules coordinate to the central YIII ion directly. From the res
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