STUDY ON PREPARATION, COMPLEX PERMITTIVITY,PERMEABILITY AND MICROWAVE PROPERTIES OF BaZnzCo2- zFe16O27/SiO2 MICROCRYSTALLINE GLASS CERAMICS
来源期刊:Acta Metallurgica Sinica2003年第6期
论文作者:L.Y.Zhang X.Yao X.L.Jia H.J.Zhang
Key words:BaZnzCo2 zFe16O27/SiO2; microcrystalline glass ceramics; sol-gel; microwave property;
Abstract: BaZnz Co2- z Fe16 O27 /SiO2 microcrystalline glass ceramics with Z=0.0, 0.5, 0.8 and 1.1 were prepared at temperature 1200℃ for 5h by citrate sol-gel process. The complex dielectric constant and complex permeability of BaZnzCo2-zFe16O27/SiO2-paraffin wax composites had been measured. Both the complex dielectric constant and dielectric loss exhibit almost no variation with frequency in 0.1-6.0GHz. The real part of permeability decreases with increasing frequency for all samples, and the imaginary part of permeability exhibits a clear resonance peak at 1.44GHz for Co2 W/SiO2,1.32GHz for Zn0.5 Co1.5 W/SiO2, 1.20GHz for Zn0.8Co1.2 W/SiO2, and 1.08GHz for Zn1.1 Co0.9 W/SiO2. It is also showed that the content of zinc has a close effect on the magnetic properties of BaZnz Co2-zFe16 O27/SiO2 microcrystalline glass ceramics,the greater the zinc content, the higher the values of imaginary part of permeability and magnetic loss.
L.Y.Zhang1,X.Yao1,X.L.Jia2,H.J.Zhang2
(1.Functional Materials Research Laboratory, Tongji University, Shanghai 200092, China;
2.High Temperature Ceramics Institute, Zhengzhou University, Zhengzhou 450052)
Abstract:BaZnz Co2- z Fe16 O27 /SiO2 microcrystalline glass ceramics with Z=0.0, 0.5, 0.8 and 1.1 were prepared at temperature 1200℃ for 5h by citrate sol-gel process. The complex dielectric constant and complex permeability of BaZnzCo2-zFe16O27/SiO2-paraffin wax composites had been measured. Both the complex dielectric constant and dielectric loss exhibit almost no variation with frequency in 0.1-6.0GHz. The real part of permeability decreases with increasing frequency for all samples, and the imaginary part of permeability exhibits a clear resonance peak at 1.44GHz for Co2 W/SiO2,1.32GHz for Zn0.5 Co1.5 W/SiO2, 1.20GHz for Zn0.8Co1.2 W/SiO2, and 1.08GHz for Zn1.1 Co0.9 W/SiO2. It is also showed that the content of zinc has a close effect on the magnetic properties of BaZnz Co2-zFe16 O27/SiO2 microcrystalline glass ceramics,the greater the zinc content, the higher the values of imaginary part of permeability and magnetic loss.
Key words:BaZnzCo2 zFe16O27/SiO2; microcrystalline glass ceramics; sol-gel; microwave property;
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