Wear and Corrosion Properties of Mo Surface-modified Layer in TiNi Alloy Prepared by Plasma Surface Alloying
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2016年第4期
论文作者：张红前 WANG Zhenxia YANG Hongyu SHAN Xiaolin LIU Xiaoping YU Shengwang 贺志勇
文章页码：910 - 917
摘 要：In order to improve the wear resistance and restrain nickel release of TiNi alloys,the Mo modified layers on TiNi substrates were obtained using the double glow plasma surface alloying technique.Scanning electron microscopy（SEM）,glow discharge optical emission spectroscopy（GDOES） and X-ray diffraction（XRD） were employed to investigate the morphology,composition and structure.Microhardness test and scratch test were performed to analyze the microhardness and coating/substrate adhesion.Tribological and electrochemical behaviors of the Mo modified layers on TiNi were tested by the reciprocating wear instrument and electrochemical measurement system.The Ni concentrations in Hanks’ solution where surface electrochemical tests took place were measured by mass spectrometry.The surface-modified layer contained a Mo deposition layer and a Mo diffusion layer.The X-ray diffraction analysis revealed that the modified layers were composed of Mo,MoTi,Mo Ni,and Ti2Ni.The microhardnesses of the Mo modified layers treated at 900 ℃ and 950 ℃ were 832.8 HV and 762.4 HV,respectively,which was about 3 times the microhardness of the TiNi substrate.Scratch tests indicated that the modified layers possessed good adhesion with the substrate.Compared with as-received TiNi alloy,the modified alloys exhibited significant improvement of wear resistance against Si3N4 with low normal loads during the sliding tests.Mass spectrometry displayed that the Mo alloy layers had successfully inhibited the Ni release into the body.
张红前1,2，WANG Zhenxia1，YANG Hongyu1，SHAN Xiaolin1，LIU Xiaoping1，YU Shengwang1，贺志勇1
1. Research Institute of Surface Engineering,Taiyuan University of Technology2. Research and Development Center of Mold Division,Chongqing Changan Automobile Limited Company
摘 要：In order to improve the wear resistance and restrain nickel release of TiNi alloys,the Mo modified layers on TiNi substrates were obtained using the double glow plasma surface alloying technique.Scanning electron microscopy（SEM）,glow discharge optical emission spectroscopy（GDOES） and X-ray diffraction（XRD） were employed to investigate the morphology,composition and structure.Microhardness test and scratch test were performed to analyze the microhardness and coating/substrate adhesion.Tribological and electrochemical behaviors of the Mo modified layers on TiNi were tested by the reciprocating wear instrument and electrochemical measurement system.The Ni concentrations in Hanks’ solution where surface electrochemical tests took place were measured by mass spectrometry.The surface-modified layer contained a Mo deposition layer and a Mo diffusion layer.The X-ray diffraction analysis revealed that the modified layers were composed of Mo,MoTi,Mo Ni,and Ti2Ni.The microhardnesses of the Mo modified layers treated at 900 ℃ and 950 ℃ were 832.8 HV and 762.4 HV,respectively,which was about 3 times the microhardness of the TiNi substrate.Scratch tests indicated that the modified layers possessed good adhesion with the substrate.Compared with as-received TiNi alloy,the modified alloys exhibited significant improvement of wear resistance against Si3N4 with low normal loads during the sliding tests.Mass spectrometry displayed that the Mo alloy layers had successfully inhibited the Ni release into the body.
关键词：
