Effect of samarium doping on structural, optical and magnetic properties of vertically aligned ZnO nanorod arrays
来源期刊：JOURNAL OF RARE EARTHS2017年第10期
论文作者：D.Ranjith Kumar K.S.Ranjith L.R.Nivedita R.T.Rajendra Kumar
文章页码：1002 - 1007
摘 要：Samarium doped vertically aligned one dimensional ZnO nanorod（NR） arrays were grown by vapor phase transport（VPT） method through vapor solid（VS） growth process. Influence of different concentrations（0% to 8%） of Sm（all Sm contents in the paper are in mass fraction） on the ZnO NR arrays were investigated by X-ray diffraction（XRD）, field emission scanning electron microscopy（FESEM）, photoluminescence（PL）, Raman spectroscopy and vibrating sample magnetometry（VSM） techniques, respectively. X-ray diffraction studies revealed that the ZnO NR arrays were perfectly oriented along（002） crystallographic orientation with wurtzite crystal structure. Photoluminescence results showed an increase in oxygen vacancies due to increase in Sm doping. M-H curves revealed enhanced ferromagnetic behavior, and the magnetic moment values were 0.45, 0.363, 1.694, 3.613 and 2.197 emu/cm3 for（0–8%） Sm doped ZnO NR arrays respectively. The curve revealed that paramagnetic behavior was observed for undoped ZnO NR arrays and on increasing the Sm dopant to 4%, paramagnetic switched to ferromagnetic behavior.
D.Ranjith Kumar1，K.S.Ranjith2，L.R.Nivedita2，R.T.Rajendra Kumar1,2
1. Department of Nanoscience and Technology, Bharathiar University2. Advanced Materials and Devices Laboratory (AMDL), Department of Physics, Bharathiar University
摘 要：Samarium doped vertically aligned one dimensional ZnO nanorod（NR） arrays were grown by vapor phase transport（VPT） method through vapor solid（VS） growth process. Influence of different concentrations（0% to 8%） of Sm（all Sm contents in the paper are in mass fraction） on the ZnO NR arrays were investigated by X-ray diffraction（XRD）, field emission scanning electron microscopy（FESEM）, photoluminescence（PL）, Raman spectroscopy and vibrating sample magnetometry（VSM） techniques, respectively. X-ray diffraction studies revealed that the ZnO NR arrays were perfectly oriented along（002） crystallographic orientation with wurtzite crystal structure. Photoluminescence results showed an increase in oxygen vacancies due to increase in Sm doping. M-H curves revealed enhanced ferromagnetic behavior, and the magnetic moment values were 0.45, 0.363, 1.694, 3.613 and 2.197 emu/cm3 for（0–8%） Sm doped ZnO NR arrays respectively. The curve revealed that paramagnetic behavior was observed for undoped ZnO NR arrays and on increasing the Sm dopant to 4%, paramagnetic switched to ferromagnetic behavior.
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