Spectrophotometric determination of platinum after solid-liquid extraction with 1-（2-pyridylazo）-2-naphthol at 90°C
来源期刊：Rare Metals2004年第3期
论文作者：DONG Yanjie, GAI Ke, and GONG Xingxin Department of Chemistry, Longdong University, Qingyang , China
文章页码：197 - 202
摘 要：<正> An effective spectrophotometric determination of platinum with 1-（2-pyridylazo）-2-naphthol （PAN） using molten naphthalene as a diluent was studied. A green complex of platinum with PAN is formed at 90℃. In the range of pH 2.5-6.5, the complex is quantitatively extracted into molten naphthalene. The organic phase is anhydrously dissolved in CHCl3 to be determined spectrophotometrically at 690 nm against the reagent blank. Beer’s law is obeyed over the concentration range of 0.5-5.0μtg/mL. The molar absorptivity and Sandell’s sensitivity are 1.6×105 L·mol-1·cm-1 and 0.0048 mg.cm-2, respectively. The optimum conditions for determination are obtained, The interferences of various ions are observed in detail. The method has been applied to the determination of platinum in synthetic samples.
DONG Yanjie, GAI Ke, and GONG Xingxin Department of Chemistry, Longdong University, Qingyang 745000, China
摘 要：<正> An effective spectrophotometric determination of platinum with 1-（2-pyridylazo）-2-naphthol （PAN） using molten naphthalene as a diluent was studied. A green complex of platinum with PAN is formed at 90℃. In the range of pH 2.5-6.5, the complex is quantitatively extracted into molten naphthalene. The organic phase is anhydrously dissolved in CHCl3 to be determined spectrophotometrically at 690 nm against the reagent blank. Beer’s law is obeyed over the concentration range of 0.5-5.0μtg/mL. The molar absorptivity and Sandell’s sensitivity are 1.6×105 L·mol-1·cm-1 and 0.0048 mg.cm-2, respectively. The optimum conditions for determination are obtained, The interferences of various ions are observed in detail. The method has been applied to the determination of platinum in synthetic samples.
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