Synthesis of A Novel UV-curable Oligmer 1,4-cyclohexanedimethanol Glycidyl Ether Acrylate and Study on Its UV-curing Properties
来源期刊:Journal Of Wuhan University Of Technology Materials Science Edition2014年第6期
论文作者:黄笔武 DENG Chong XU Qinchang CHEN Weiqing ZOU Huaihua
文章页码:1283 - 1289
摘 要:A novel UV-curable oligmer 1,4-cyclohexanedimethanol glycidyl ether acrylate(CHDMGEA) was synthesized by utilizing 1,4-cyclohexanedimethanol glycidyl ether(CHDMGE) and acrylic acid(AA) as starting materials, triphenyl phosphine as catalyst and p-hydroxyanisole as inhibitor. The optimum synthetic conditions were that the concentration of triphenyl phosphine was 0.90% of reactants by weight, the concentration of p-hydroxyanisole was 0.20% of reactants by weight, the reaction temperature was 90-100 ℃, and the molar ratio of CHDMGE to AA was 0.5:1.1. The experimental results show that CHDMGEA is a kind of good UV-curable oligmer. The impact resistance of the UV-cured films with CHDMGEA as oligmer to prepare UV-curing coating was superior to that of the UV-cured films with bisphenol A diglycidyl ether diacrylate(BPGEA) as oligmer to prepare UV-curing coating.
黄笔武,DENG Chong,XU Qinchang,CHEN Weiqing,ZOU Huaihua
School of Materials Science and Engineering, Nanchang University
摘 要:A novel UV-curable oligmer 1,4-cyclohexanedimethanol glycidyl ether acrylate(CHDMGEA) was synthesized by utilizing 1,4-cyclohexanedimethanol glycidyl ether(CHDMGE) and acrylic acid(AA) as starting materials, triphenyl phosphine as catalyst and p-hydroxyanisole as inhibitor. The optimum synthetic conditions were that the concentration of triphenyl phosphine was 0.90% of reactants by weight, the concentration of p-hydroxyanisole was 0.20% of reactants by weight, the reaction temperature was 90-100 ℃, and the molar ratio of CHDMGE to AA was 0.5:1.1. The experimental results show that CHDMGEA is a kind of good UV-curable oligmer. The impact resistance of the UV-cured films with CHDMGEA as oligmer to prepare UV-curing coating was superior to that of the UV-cured films with bisphenol A diglycidyl ether diacrylate(BPGEA) as oligmer to prepare UV-curing coating.
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