Microscopic Evidence of Destroying the Order of Magnetic Sequence in CuO2 Chain by Zn, Ni, Co Doping in Sr14Cu24O41 Compound
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2013年第6期
论文作者：WANG Jun ZOU Huamin LI Yang XIE Hui HU Ni WANG Lili SHI Jing
文章页码：1068 - 1075
摘 要：The Zn2+, Ni2+and Co3+doped Sr 14 Cu 24 O 41 compounds were synthesized by standard solid state method. X-ray diffraction results show that the changes in lattice parameters are very small. Selected area electron diffraction patterns（EDPs） show that the diffraction spots corresponding to the CuO 2 chain substructure are extended to streaks along a* and b* directions for all the samples, while the diffraction spots produced merely by the Cu 2 O 3 ladder substructure are still very sharp. This means that the periodicities of chains in a* and b* directions are partially destroyed upon doping of Zn, Ni and Co due to that the initial phase of each chain becomes a random variable. The temperature dependence of magnetic properties was measured for every sample. And the number of dimers in CuO 2 chain per formula unit（f.u.） and dimer coupling constant are obtained by fitting the temperature dependence of the magnetic susceptibility. It is found that the degree of initial phase disorder is related to the order degree of magnetic sequence in CuO 2 chain. For the un-doped sample, the decoupling of dimers is weak, the magnetic sequence is slightly destroyed, and the streaks in EDP are also very weak, which implies the degree of initial phase disorder in CuO 2 chain is very low. When Zn2+and Ni2+ions are doped, the number of dimers per f.u. decreases, and the intensity of diffraction streaks increases in comparison with the corresponding spots. Furthermore, when the high spin magnetic ions Co3+are doped, the number of holes in Sr 14 Cu 24 O 41 decreases, the magnetic sequence is destroyed very seriously, and the spots in EDP are extended to streaks almost completely. The phenomenon that the diffraction spots of CuO 2 chain extend to streaks in EDP appears as evidence that the magnetic sequence in the CuO 2 chain is destroyed by doping of Zn, Ni, Co.
WANG Jun1,2,3，ZOU Huamin1,2，LI Yang1,2，XIE Hui1，HU Ni1，WANG Lili1，SHI Jing1
1. Key Laboratory of Acoustic and Photonic Material and Device,Ministry of Education,Department of Physics,Wuhan University2. Centre for Electron Microscopy,Wuhan University3. Three Gorges Vocational College of Electric Power
摘 要：The Zn2+, Ni2+and Co3+doped Sr 14 Cu 24 O 41 compounds were synthesized by standard solid state method. X-ray diffraction results show that the changes in lattice parameters are very small. Selected area electron diffraction patterns（EDPs） show that the diffraction spots corresponding to the CuO 2 chain substructure are extended to streaks along a* and b* directions for all the samples, while the diffraction spots produced merely by the Cu 2 O 3 ladder substructure are still very sharp. This means that the periodicities of chains in a* and b* directions are partially destroyed upon doping of Zn, Ni and Co due to that the initial phase of each chain becomes a random variable. The temperature dependence of magnetic properties was measured for every sample. And the number of dimers in CuO 2 chain per formula unit（f.u.） and dimer coupling constant are obtained by fitting the temperature dependence of the magnetic susceptibility. It is found that the degree of initial phase disorder is related to the order degree of magnetic sequence in CuO 2 chain. For the un-doped sample, the decoupling of dimers is weak, the magnetic sequence is slightly destroyed, and the streaks in EDP are also very weak, which implies the degree of initial phase disorder in CuO 2 chain is very low. When Zn2+and Ni2+ions are doped, the number of dimers per f.u. decreases, and the intensity of diffraction streaks increases in comparison with the corresponding spots. Furthermore, when the high spin magnetic ions Co3+are doped, the number of holes in Sr 14 Cu 24 O 41 decreases, the magnetic sequence is destroyed very seriously, and the spots in EDP are extended to streaks almost completely. The phenomenon that the diffraction spots of CuO 2 chain extend to streaks in EDP appears as evidence that the magnetic sequence in the CuO 2 chain is destroyed by doping of Zn, Ni, Co.
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