Synthesis and Properties of Rare Earth Complexes with 3-Ferrocenyl-5-Phenyl-Pyrazoline-1-Dithiocarbamate
来源期刊:Journal of Rare Earths1993年第2期
论文作者:鲁文杰 王星堂 韩晓军 陈敏
文章页码:85 - 88
摘 要:<正> Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrousrare earth chlorides in absolute ethanol to give 14 new complexes.The results of elemental analysis show thatthe compositions of the complexes are RE(FPPD)3·nH2O(RE=La,Pr~Lu and Y;n=3).The ligand andits complexes have been characterized by infrared spectroscopy,UV-visible absorptionspectroscopy,1H-NMR spectra,thermal analysis and molar conductivity measurement.
鲁文杰,王星堂,韩晓军,陈敏
摘 要:<正> Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrousrare earth chlorides in absolute ethanol to give 14 new complexes.The results of elemental analysis show thatthe compositions of the complexes are RE(FPPD)3·nH2O(RE=La,Pr~Lu and Y;n=3).The ligand andits complexes have been characterized by infrared spectroscopy,UV-visible absorptionspectroscopy,1H-NMR spectra,thermal analysis and molar conductivity measurement.
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