Synthesis and luminescent properties of Eu3+-doped Na24As2W22O83
来源期刊:Rare Metals2003年第2期
论文作者:YANG Shuijin, YUAN Liangjie, and SUN Jutang) Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi , China) College of Chemistry and Molecular Sciences, Wuhan University, Wuhan , China (Received---)
文章页码:95 - 97
摘 要:<正> The Eu3+-doped Na24As2W22O83 phosphor has been prepared by solid state reaction from Na3AsO412H2O, Na2WO4 2H2O and WO3, and characterized by elemental analysis, infrared spectroscopy and powder X-ray diffractometry. According to the measurements with X-ray diffraction, this material belongs to orthorhombic system with its lattice constants: a = 1.4750 nm, b = 1.1944 nm, c = 1.1062 nm, it is consistent with space group D24-P212121 (No.19). The emission and excitation spectra were measured. The luminescent properties of Eu3+-doped Na24As2W22O83 and mechanism of energy transfer were discussed.
YANG Shuijin, YUAN Liangjie, and SUN Jutang1) Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China2) College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China (Received-2002-03-28)
摘 要:<正> The Eu3+-doped Na24As2W22O83 phosphor has been prepared by solid state reaction from Na3AsO412H2O, Na2WO4 2H2O and WO3, and characterized by elemental analysis, infrared spectroscopy and powder X-ray diffractometry. According to the measurements with X-ray diffraction, this material belongs to orthorhombic system with its lattice constants: a = 1.4750 nm, b = 1.1944 nm, c = 1.1062 nm, it is consistent with space group D24-P212121 (No.19). The emission and excitation spectra were measured. The luminescent properties of Eu3+-doped Na24As2W22O83 and mechanism of energy transfer were discussed.
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