Effect of Modified Vermiculite on the Interface of a Capric Acid-expanded Vermiculite Composite Phase Change Material with Phase Transition Kinetics
来源期刊:Journal Of Wuhan University Of Technology Materials Science Edition2019年第2期
论文作者:张弘光 朱教群 CHENG Xiaomin ZHOU Weibing LIU Fengli
文章页码:345 - 352
摘 要:A new type of capric acid(CA)-acid expanded vermiculite(AEV) composite phase change material(PCM) with improved adsorption ability and interface adhesive strength was developed. Through the analysis of non-isothermal phase transition kinetics, modified vermiculite was observed to change and affect the phase transformation mechanism of the composite. AEV was treated with hydrochloric acid to improve the specific surface area and micro-pore structure. The surface area measured by BET increased from 81.94 m2/g for expanded vermiculite(EV) to 544.13 m2/g for AEV. CA-EV and CA-AEV composite PCMs were prepared by direct impregnation. The non-isothermal phase transition isotherms of CA-EV and CA-AEV were recorded by DSC at different heating rates(1, 5, 10, 15, and 20 ℃/min), which indicated that the phase transition rate increased with the heating rate and the phase transition process changed. Kinetics parameters were analyzed by a double extrapolation method. The activation energy(E) under the original state(Eα→0) of CA-AEV and CA-EV was 1 117 kJ/mol and 937 kJ/mol, respectively, and 1 205 kJ/mol and 1 016 kJ/mol under the thermal equilibrium state(Eβ→0). The most probabilistic mechanism function of CA-AEV satisfied G(α)=α2/3, which followed the Mample special rule, and the function of CA-EV satisfied G(α)=[(1+α)1/3-1]2, which followed the anti-Jander function.
张弘光1,2,朱教群1,2,CHENG Xiaomin2,ZHOU Weibing1,2,LIU Fengli1,2
1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology2. School of Materials Science and Engineering, Wuhan University of Technology
摘 要:A new type of capric acid(CA)-acid expanded vermiculite(AEV) composite phase change material(PCM) with improved adsorption ability and interface adhesive strength was developed. Through the analysis of non-isothermal phase transition kinetics, modified vermiculite was observed to change and affect the phase transformation mechanism of the composite. AEV was treated with hydrochloric acid to improve the specific surface area and micro-pore structure. The surface area measured by BET increased from 81.94 m2/g for expanded vermiculite(EV) to 544.13 m2/g for AEV. CA-EV and CA-AEV composite PCMs were prepared by direct impregnation. The non-isothermal phase transition isotherms of CA-EV and CA-AEV were recorded by DSC at different heating rates(1, 5, 10, 15, and 20 ℃/min), which indicated that the phase transition rate increased with the heating rate and the phase transition process changed. Kinetics parameters were analyzed by a double extrapolation method. The activation energy(E) under the original state(Eα→0) of CA-AEV and CA-EV was 1 117 kJ/mol and 937 kJ/mol, respectively, and 1 205 kJ/mol and 1 016 kJ/mol under the thermal equilibrium state(Eβ→0). The most probabilistic mechanism function of CA-AEV satisfied G(α)=α2/3, which followed the Mample special rule, and the function of CA-EV satisfied G(α)=[(1+α)1/3-1]2, which followed the anti-Jander function.
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