Cu—Fe—S—Cl^-—H₂O系的热力学平衡及其电位—pH图（25℃）

来源期刊：中南大学学报(自然科学版)1982年第1期

论文作者：黄振谦

文章页码：29 - 38

关键词：热力学平衡； 电位差； 热力学分析； 热力学原理； 黄铜矿； 自由度； 络离子； 稳定区； 虚线； 氯量

摘    要：本文基于溶液各组成同时处于平衡的热力学原理,分析了 Cu—Fe—s—Cl^-—H₂O 系的热力学平衡,从而绘制了黄铜矿—Cl^-—H₂O 系的电位—pH 图。从热力学分析表明,当氯含量在一定范围内,该体系出现一个 CuCl_（s）稳定区。氯量过低或过高,CuCl_（s）都会消失。文中还讨论了从 Cu—Fe—S—Cl^-—H₂O 系中获得 CuCl_（s）的可能性。

Abstract: Based on the thermodynamic principle that all species of solution are in simultaneous equilibrium,this paper has analyzed the thermodynamic equi- librium of Cu—Fe—S—Cl—H₂O system and represented it by constructing the potential—pH diagram of chalcopyrite-Cl^--H₂O system.The thermo- dynamic analysis indicates that when the chlorine content of solution is wi- thin a certain limit,there will appear a stable region of CuCl_s,in the system.With too high or too low a chlorine content,CuCl_s,will not appear. At the same time,the possibility of obtaining CuCl_s,from Cu-Fe-S-Cl^-- -H₂O system has also been discussed in this paper.