Supporting of Nickel(Ⅱ) Acenaphthenediimine with Free Amino Group for Ethylene Polymerization
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2010年第2期
论文作者：胡扬剑
文章页码：260 - 264
摘 要：Bis （4-（4-amino-3, 5-diethylbenzyl）-2, 6-diethylphenylimino） acenaphthene] di- chloronickel （NiLCl2） was prepared and supported on SiO2 modified by methyl trichlorsilane（S-1） and on SiO2-MgCl2/TiCl4 （S-2） respectively. Two supported catalysts S-1 and S-2 used as catalysts for ethylene polymerization were studied and the influences of various polymerization conditions, including the polymerization temperature, cocatalysts, Al/Ni molar ratio on the catalytic activity, branching degree and branch length of PE were also investigated. The experimental results show that the supported catalysts exhibit higher catalytic activity for ethylene polymerization, the highest catalytic activity of S-1 using AlEt2Cl as cocatalyst at 50 ℃, reaching 5.8×105gPE/molNi·h, and needed lower Al/Ni molar ratio compared to homogeneous analogue.
胡扬剑
Department of Chemistry and Chemical Engineering, Huaihua College
摘 要：Bis （4-（4-amino-3, 5-diethylbenzyl）-2, 6-diethylphenylimino） acenaphthene] di- chloronickel （NiLCl2） was prepared and supported on SiO2 modified by methyl trichlorsilane（S-1） and on SiO2-MgCl2/TiCl4 （S-2） respectively. Two supported catalysts S-1 and S-2 used as catalysts for ethylene polymerization were studied and the influences of various polymerization conditions, including the polymerization temperature, cocatalysts, Al/Ni molar ratio on the catalytic activity, branching degree and branch length of PE were also investigated. The experimental results show that the supported catalysts exhibit higher catalytic activity for ethylene polymerization, the highest catalytic activity of S-1 using AlEt2Cl as cocatalyst at 50 ℃, reaching 5.8×105gPE/molNi·h, and needed lower Al/Ni molar ratio compared to homogeneous analogue.
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