Synthesis of micrometer SrAl2Si2O8 :Eu, Dy blue phosphor powders via sol- gel process
来源期刊：功能材料与器件学报2008年第1期
论文作者：潘文 宁桂玲
关键词：Sol - gel method; Luminescence; Phosphors; SrAl2Si2O8 : Eu2+,Dy3+;
摘 要：In this paper, we report on long- persistence white phosphor SrAl2Si2O8 :Eu2+ , Dy3+ synthe-sized by the sol - gel method. The luminescent materials prepared by the sol - gel method have many ad-vantages, such as uniform composition, high purity, fine grains and low synthesis temperature. We foundthat SrAl2Si2O8 :Eu2+ ,Dy3+ phosphor prepared by the sol -gel method can provide more luminescent in-tensity and better afterglow characteristic compared with the same phosphor prepared by solid -statemethod. Namely, the particle size and shape of phosphors should be optimized to obtain the maximumquantum efficiency through energy absorption. The mierostrueture of the phosphor consisted of regularfine grains with an average size of about 0.5. - 1 μm. Under 356 nm light excitation, the broadband emis-sion of the phosphor continues from 350 to 650 ntn and the emission peak is at about 414 nm, which canbe viewed as the typical emission of Eu2+ ascribed to the 4f→5d transitions.
潘文1，宁桂玲2
(1.State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 ,China;
2.大连理工大学化工学院)
摘要:In this paper, we report on long- persistence white phosphor SrAl2Si2O8 :Eu2+ , Dy3+ synthe-sized by the sol - gel method. The luminescent materials prepared by the sol - gel method have many ad-vantages, such as uniform composition, high purity, fine grains and low synthesis temperature. We foundthat SrAl2Si2O8 :Eu2+ ,Dy3+ phosphor prepared by the sol -gel method can provide more luminescent in-tensity and better afterglow characteristic compared with the same phosphor prepared by solid -statemethod. Namely, the particle size and shape of phosphors should be optimized to obtain the maximumquantum efficiency through energy absorption. The mierostrueture of the phosphor consisted of regularfine grains with an average size of about 0.5. - 1 μm. Under 356 nm light excitation, the broadband emis-sion of the phosphor continues from 350 to 650 ntn and the emission peak is at about 414 nm, which canbe viewed as the typical emission of Eu2+ ascribed to the 4f→5d transitions.
关键词:Sol - gel method; Luminescence; Phosphors; SrAl2Si2O8 : Eu2+,Dy3+;
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