STUDY ON SYNTHESIS,CHARACTERIZATION AND STRUCTURE OF A NEW RARE EARTH COORDINATION COMPOUND WITH BENZOIC ACID
来源期刊：Journal of Rare Earths1990年第2期
论文作者：段治邦 金钟声 胡宁海 倪嘉缵
文章页码：81 - 86
摘 要：<正> In this paper,a new rare earth benzoate coordination compound,[TbL3（HL）（H2O）]2（HL=C7H6O2=benzoic acid） is synthesized and characterized by elemental analysis DTA,TG,DTC,and IRspectra.The title compound crystallizes in triclinic,space.group P with a=9.148（1）,b=11.460（2）,c=13.506（2）;α=112.76（1）,β=91.83（1）,γ=91.99（1）°;Z=1;V=1303.3.The final R factor is0.0235.The rare earth ion is nine-coordinated to form a distorted monocapped square antiprism.
段治邦，金钟声，胡宁海，倪嘉缵
摘 要：<正> In this paper,a new rare earth benzoate coordination compound,[TbL3（HL）（H2O）]2（HL=C7H6O2=benzoic acid） is synthesized and characterized by elemental analysis DTA,TG,DTC,and IRspectra.The title compound crystallizes in triclinic,space.group P with a=9.148（1）,b=11.460（2）,c=13.506（2）;α=112.76（1）,β=91.83（1）,γ=91.99（1）°;Z=1;V=1303.3.The final R factor is0.0235.The rare earth ion is nine-coordinated to form a distorted monocapped square antiprism.
关键词：
