简介概要

Effect of glass network modifier R2O(R=Li, Na and K) on upconversion luminescence in Er3+/Yb3+ co-doped NaYF4 oxyfluoride glass-ceramics

来源期刊:JOURNAL OF RARE EARTHS2015年第8期

论文作者:高源 胡曰博 任鹏 周大成 邱建备

文章页码:830 - 836

摘    要:The effect of glass network modifier R2O(R=Li, Na, K) on upconversion luminescence in Er3+/Yb3+ co-doped Na YF4 oxyfluoride glass-ceramics was investigated. NaY F4 nanocrystals with different sizes were studied under glass network modifier alkali mental oxide. The nanocrystals size in NaY F4 of Li2 O modified samples was 11 nm, whereas in the Na2 O and K2 O modified sample, the crystal size was 25 and 43 nm, respectively. It was found that red, yellow and green upconversions were observed in SAL, SAN, SAK glass ceramics. The reported results would deepen the understanding of size effects on the lanthanide upconversion in nanocrystals.

详情信息展示

Effect of glass network modifier R2O(R=Li, Na and K) on upconversion luminescence in Er3+/Yb3+ co-doped NaYF4 oxyfluoride glass-ceramics

高源1,胡曰博2,任鹏1,周大成1,3,邱建备1,3

1. Faculty of Material Science and Engineering, Kunming University of Science and Technology2. Faculty of Mechanical and Electrical Engineering, Kunming University of Science and Technology

摘 要:The effect of glass network modifier R2O(R=Li, Na, K) on upconversion luminescence in Er3+/Yb3+ co-doped Na YF4 oxyfluoride glass-ceramics was investigated. NaY F4 nanocrystals with different sizes were studied under glass network modifier alkali mental oxide. The nanocrystals size in NaY F4 of Li2 O modified samples was 11 nm, whereas in the Na2 O and K2 O modified sample, the crystal size was 25 and 43 nm, respectively. It was found that red, yellow and green upconversions were observed in SAL, SAN, SAK glass ceramics. The reported results would deepen the understanding of size effects on the lanthanide upconversion in nanocrystals.

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