Effect of thulium substitution on conductivity and dielectric belongings of nanospinel cobalt ferrite
来源期刊：JOURNAL OF RARE EARTHS2020年第10期
论文作者：B.ünal M.A.Almessiere A.Demir Korkmaz Y.Slimani A.Baykal
文章页码：1103 - 1113
摘 要：The CoTmx Fe2-x O4（x≤0.1） NPs were synthesized sonochemically.X-ray powder diffraction patterns and TEM images of the samples prove their chemical purity and cubic structure-morphology,respectively.Some substitution ratio of thulium ions to cobalt ferrites have an important effect on the characteristic evaluation of both electrical and dielectric characteristic measured at frequencies up to 3.0 MHz between room temperature and 120℃.Since the thulium substitution has a very strong effect on the characteristic evaluation of both electrical and dielectric properties of cobalt-ferrite samples,four substitutio nal ranges-none,small,medium and high were determined for the interpretation of contribution of thulium ratio to ac/dc conductivity,dielectric constant,dielectric loss and tangent loss.Conductivity increases with the incremental frequencies,in general depending on a variety of tendencies of both temperature and substitutional Tm ratios while the activation energy varies with a high dependency to the regional level of Tm substitution in Co-ferrites NPs.The Arrhenius graph appears to provide us with a single activation energy much higher than 400 meV for x=0.02,which can be attributed to electron hopping mechanisms,apart from other substituted spinel ferrites.
B.ünal1，M.A.Almessiere2,3，A.Demir Korkmaz4，Y.Slimani5，A.Baykal6
1. Institute of Forensic Sciences and Legal Medicine,Istanbul University-Cerrahpasa,Buyukcekmece Campus2. Department of Biophysics,Institute for Research & Medical Consultations (IRMC),Imam Abdulrahman Bin Faisal University3. Department of Physics,College of Science,Imam Abdulrahman Bin Faisal University4. Department of Chemistry,Istanbul Medeniyet University5. Department of Biophysics,Institute for Research & Medical Consultations ,Imam Abdulrahman Bin Faisal University6. Department of Nano-Medicine Research,Institute for Research & Medical Consultations(IRMC) ,Imam Abdulrahman Bin Faisal University
摘 要：The CoTmx Fe2-x O4（x≤0.1） NPs were synthesized sonochemically.X-ray powder diffraction patterns and TEM images of the samples prove their chemical purity and cubic structure-morphology,respectively.Some substitution ratio of thulium ions to cobalt ferrites have an important effect on the characteristic evaluation of both electrical and dielectric characteristic measured at frequencies up to 3.0 MHz between room temperature and 120℃.Since the thulium substitution has a very strong effect on the characteristic evaluation of both electrical and dielectric properties of cobalt-ferrite samples,four substitutio nal ranges-none,small,medium and high were determined for the interpretation of contribution of thulium ratio to ac/dc conductivity,dielectric constant,dielectric loss and tangent loss.Conductivity increases with the incremental frequencies,in general depending on a variety of tendencies of both temperature and substitutional Tm ratios while the activation energy varies with a high dependency to the regional level of Tm substitution in Co-ferrites NPs.The Arrhenius graph appears to provide us with a single activation energy much higher than 400 meV for x=0.02,which can be attributed to electron hopping mechanisms,apart from other substituted spinel ferrites.
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