Recovery of rare earth and cobalt from Co-based magnetic scraps
来源期刊：Journal of Rare Earths2010年第S1期
论文作者：许涛 张晓东 林忠 吕保义 马春梅 高晓玲
文章页码：485 - 488
摘 要：The reuse of RE and cobalt in Co-based magnetic scraps was studied.The optimized feat lixiviated condition was:200 mesh,sulfuric acid dosage was of 1.4 times theoretic dosage,temperature was 80 oC and leaching time 1 h.The optimum technology conditions was:Na2S2O8 dosage was of 8 times theoretic dosage,oxidation temperature 80 oC,oxidation time 2 h and pH=4.5.Rare earth was precipitated by saturated（NH4）2C2O4 solution,after roasting of rare earth oxalate,rare earth oxide was received.Cobalt-iron residue was soaked by hydrochloric acid,the Fe（OH）3 was preferential solution,pH was adjusted to 1.4 by hydrochloric acid,Co（OH）3 did not dissolve,cobalt and iron were separated,after roasting of Co（OH）3,cobalt oxide was received.The total recovery of cobalt was found to be 97% and rare earths was 96%.
许涛1,2，张晓东3，林忠4，吕保义4，马春梅5，高晓玲4
1. Baotou Research Institute of Rare Earth2. National Engineering Research Center of Rare Earth Metallurgy and Functional Materials3. Inner Mongolia Baotou Steel Rare Earth Hi-Tech Co.,Ltd.4. Baotou Environmental Protection Bureau5. School of Chemistry and Chemical Engineering,Inner Mongolia University
摘 要：The reuse of RE and cobalt in Co-based magnetic scraps was studied.The optimized feat lixiviated condition was:200 mesh,sulfuric acid dosage was of 1.4 times theoretic dosage,temperature was 80 oC and leaching time 1 h.The optimum technology conditions was:Na2S2O8 dosage was of 8 times theoretic dosage,oxidation temperature 80 oC,oxidation time 2 h and pH=4.5.Rare earth was precipitated by saturated（NH4）2C2O4 solution,after roasting of rare earth oxalate,rare earth oxide was received.Cobalt-iron residue was soaked by hydrochloric acid,the Fe（OH）3 was preferential solution,pH was adjusted to 1.4 by hydrochloric acid,Co（OH）3 did not dissolve,cobalt and iron were separated,after roasting of Co（OH）3,cobalt oxide was received.The total recovery of cobalt was found to be 97% and rare earths was 96%.
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