STUDY ON THE SOLUTION FLUORESCENCE QUENCHING FOR POLYSILANES
来源期刊：中南大学学报(英文版)1998年第1期
论文作者：Hu Huiping Huang Kelong Pan Chunyue Chen Deben
文章页码：42 - 46
Key words：polysilane; static quenching; energy migration; steady-state fluorescence
Abstract: The solution-fluorescence quenching mechanisms of poly ( methylcyclohexylsilane ), poly (methylphenethylsilane), poly(methylcyclohexylsilane-co-methylphenethylsilane) and poly(methylphenylsilane) are studied by means of steady-state fluorescence,time-resolved fluorescence and UV absorption. The results show that the fluorescence quenching for polysilanes by carbon tetrachloride is the static quenching with energy migration, which is also supported by the qualitative results of the fluorescence quenching behaviors of polysilane by nitromethane (CH3NO2) and 2, 4, 7-trinitrofluorenone(TNF).
