Leaching mechanism of sulfide ores in slurry electrolysis
来源期刊：中国有色金属学报(英文版)2000年第1期
论文作者：张英杰 杨显万 邓伦豪 姚刚
文章页码：105 - 108
Key words：leaching mechanism; sulfide mineral; slurry electrolysis
Abstract: Anodic polarization curves of sulfide mineral particle oxidation on graphite anode in slurry electrolysis have been examined to make certain of the leaching mechanism of sulfide ores in slurry electrolysis and to build up the relationship between the anodic current density, solid content in slurry and stirring speed. The results show that the leachingmechanism of sulfide minerals depends on the operating conditions. The anodic oxidation of mineral particles is the main reaction when no iron and copper ions exists in the slurry and at a low current density. In existence of iron or copper ions in slurry, the main anodic reaction is the oxidation of ferrous and cuprous ions at a low current density. At high current density, Cl- ion oxidation on anode occurs and Cl2 and HClO are produced. Sulfide leaching depends mainly on oxidation by HClO. Based on the consideration of the double layer structure and particle motion, the relationship between the anodic current density (i), solid content in slurry (cs)and stirring speed (NR)is determined asi=QcsN2R, where Q= 4π2r2nFkλ, andris the distance between stirring axis and anode surface,nis the particle number contacting with unit anodic area (1 cm2) in unit time,kthe rate constant,λthe proportional constant. Particle size does not affect the current density. The equation shows good agreement with the experimental results.
