简介概要

A novel multifunction material with both electrorheological performance and luminescence property

来源期刊:JOURNAL OF RARE EARTHS2014年第11期

论文作者:陈明星 商艳丽 贾云玲 李俊然

文章页码:1022 - 1026

摘    要:A multifunctional material with both electrorheological(ER) performance and luminescence property was synthesized by a simple coprecipitation. The tetrabutyl titanate, as well as the Tb(NO3)3·6H2O and sulphosalicylic acid(C7H6O6S·2H2O, SSA) were chosen as starting materials. The composition, ER performance and luminescence property of the material were studied. The results showed that a novel material(TiTbSSA) with both ER performance and luminescence property was obtained. The relative shear stress τr(τr=τE/τ0, τE and τ0 were the shear stresses of the suspension with and without an applied electric field) of the suspension(30 wt.%) of the material in silicone oil reached 32.7 at a shear rate of 12.5 s–1 and an electric field strength of 4 kV/mm(DC electric field). The material containing the rare earth(RE=Tb) complex exhibited fine luminescence performance and higher ER activity. Therefore, it is a novel multifunction material which would have wide application prospect.

详情信息展示

A novel multifunction material with both electrorheological performance and luminescence property

陈明星1,商艳丽2,贾云玲1,李俊然1

1. College of Chemistry and Molecular Engineering, Peking University2. College of Chemistry and Environmental Science, Hebei University

摘 要:A multifunctional material with both electrorheological(ER) performance and luminescence property was synthesized by a simple coprecipitation. The tetrabutyl titanate, as well as the Tb(NO3)3·6H2O and sulphosalicylic acid(C7H6O6S·2H2O, SSA) were chosen as starting materials. The composition, ER performance and luminescence property of the material were studied. The results showed that a novel material(TiTbSSA) with both ER performance and luminescence property was obtained. The relative shear stress τr(τr=τE/τ0, τE and τ0 were the shear stresses of the suspension with and without an applied electric field) of the suspension(30 wt.%) of the material in silicone oil reached 32.7 at a shear rate of 12.5 s–1 and an electric field strength of 4 kV/mm(DC electric field). The material containing the rare earth(RE=Tb) complex exhibited fine luminescence performance and higher ER activity. Therefore, it is a novel multifunction material which would have wide application prospect.

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