Extraction of Yttrium (Ⅲ) into [C8mim][PF6] Containing Cyanex 923
来源期刊:JOURNAL OF RARE EARTHS2007年增刊第1期
论文作者:Chen Ji Ma Jiutong Sun Xiaoqi
Key words:room temperature ionic liquid; extraction; Cyanex 923; yttrium;
Abstract: The extraction of Yttrium (Ⅲ) into [Cnmim] [PF6] (n=4,6,8) containing Cyanex 923 was studied in this paper. The mechanism of this extraction was indicated to be cation exchange. In addition, the extraction process is an endothermic reaction. The RTILs with shorter alkyl chain behave higher extraction efficiency during the extraction, however, which has also more loss to aqueous phase since the cation exchange mechanism.
Chen Ji1,Ma Jiutong2,Peng Bo2,Sun Xiaoqi1
(1.Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Graduate School from Chinese Academy of Science, Chinese Academy of Science, Changchun 130022, China;
2.College of Chemistry, Jilin University, Changchun 130061, China)
Abstract:The extraction of Yttrium (Ⅲ) into [Cnmim] [PF6] (n=4,6,8) containing Cyanex 923 was studied in this paper. The mechanism of this extraction was indicated to be cation exchange. In addition, the extraction process is an endothermic reaction. The RTILs with shorter alkyl chain behave higher extraction efficiency during the extraction, however, which has also more loss to aqueous phase since the cation exchange mechanism.
Key words:room temperature ionic liquid; extraction; Cyanex 923; yttrium;
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