Preparation of Ce0.65Zr0.35O2 by co-precipitation: The role of hydrogen peroxide
来源期刊：JOURNAL OF RARE EARTHS2013年第5期
论文作者：黄利华 陈山虎 朱艺 龚茂初 陈耀强
文章页码：461 - 469
摘 要：The effect of H2O2 on the properties of Ce0.65Zr0.35O2 was explored by treating cerium nitrate and zirconium nitrate with a mixed aqueous solution of ammonia and ammonia-carbonate in the presence/absence of H2O2 . The resultant products were characterized by X-ray diffraction （XRD）, X-ray photoelectron spectroscopy （XPS）, nitrogen adsorption/desorption, oxygen storage capacity （OSC） and H2-temperature-programmed reduction （H2-TPR）. The presence of H2O2 was found to have profound effect on powder properties such as surface area, crystallite size of the samples. It was also shown that the addition of H2O2 favored the incorporation of Zr4+ into CeO2 lattice, which facilitated the formation of CeO2-ZrO2 solid solution, and enhanced the thermal stability of the samples. OSC and H2-TPR studies indicated that the use of H2O2 enhanced the OSC and redox properties. Catalytic activity tests showed that as a support, the Ce0.65Zr0.35O2 prepared in the presence of H2O2 was more suitable for three-way catalyst. The corresponding Pd-only three-way catalyst demonstrated outstanding performance: wide air to fuel operation window, low light-off and total conversion temperature for the conversion of C3H8, NO and CO.
黄利华1,2，陈山虎3，朱艺3，龚茂初3，陈耀强1,3
1. Department of Architecture and Environment,Sichuan University2. Insititute of Environment and Resources,Southwest University of Science and Technology3. Key Laboratory of Green Chemistry & Technology of the Ministry of Education
摘 要：The effect of H2O2 on the properties of Ce0.65Zr0.35O2 was explored by treating cerium nitrate and zirconium nitrate with a mixed aqueous solution of ammonia and ammonia-carbonate in the presence/absence of H2O2 . The resultant products were characterized by X-ray diffraction （XRD）, X-ray photoelectron spectroscopy （XPS）, nitrogen adsorption/desorption, oxygen storage capacity （OSC） and H2-temperature-programmed reduction （H2-TPR）. The presence of H2O2 was found to have profound effect on powder properties such as surface area, crystallite size of the samples. It was also shown that the addition of H2O2 favored the incorporation of Zr4+ into CeO2 lattice, which facilitated the formation of CeO2-ZrO2 solid solution, and enhanced the thermal stability of the samples. OSC and H2-TPR studies indicated that the use of H2O2 enhanced the OSC and redox properties. Catalytic activity tests showed that as a support, the Ce0.65Zr0.35O2 prepared in the presence of H2O2 was more suitable for three-way catalyst. The corresponding Pd-only three-way catalyst demonstrated outstanding performance: wide air to fuel operation window, low light-off and total conversion temperature for the conversion of C3H8, NO and CO.
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