Magnetic transitions and butterfly-shaped hysteresis of Sm-Fe-Al-based perovskite-type orthoferrite
来源期刊：JOURNAL OF RARE EARTHS2015年第9期
论文作者：M.A.Ahmed N.G.Imam 郭向欣 Y.A.Saeid
文章页码：965 - 971
摘 要：Al doped SmFeO3（Sm Fe1–x Al x O3; 0.0￡x￡0.15; step 0.05） were prepared by double sintering ceramic technique. The obtained samples were crystallized in single phase structure except the sample with x=0.15. The unit cell volume was found to decrease with increasing Al substitution in orthoferrite. The effective magnetic moment（meff） and the Curie constant（C） were calculated from the reciprocal of the molar magnetic susceptibility（χ–1） versus absolute temperature plot and found to attain maximum value for the parent sample. The magnetic behavior showed two different magnetic transitions, viz, Néel temperature（T N） and spin reorientation（T SR） transitions. The M-H hysteresis loop of the parent sample took butterfly-shape as a result of different contributions anisotropies. From the magnetic properties measurements, it was obviously found that B-site cation dilution resulted in a drastic decrease in the magnetization. Surprisingly large value of the coercive field was obtained for the undoped sample; H c=6198.8 Oe. Based on the mentioned results, one can recommend the use of such orthoferrite in magnetic recording media and as pining layer in spin valve for spintronic applications.
M.A.Ahmed1，N.G.Imam2，M.K.Abdelmaksoud1，Y.A.Saeid1
1. Materials Science Lab. Physics Department, Faculty of Science, Cairo University2. Materials Science Lab. Experimental Physics Department, Nuclear Research Center, Atomic Energy Authority
摘 要：Al doped SmFeO3（Sm Fe1–x Al x O3; 0.0￡x￡0.15; step 0.05） were prepared by double sintering ceramic technique. The obtained samples were crystallized in single phase structure except the sample with x=0.15. The unit cell volume was found to decrease with increasing Al substitution in orthoferrite. The effective magnetic moment（meff） and the Curie constant（C） were calculated from the reciprocal of the molar magnetic susceptibility（χ–1） versus absolute temperature plot and found to attain maximum value for the parent sample. The magnetic behavior showed two different magnetic transitions, viz, Néel temperature（T N） and spin reorientation（T SR） transitions. The M-H hysteresis loop of the parent sample took butterfly-shape as a result of different contributions anisotropies. From the magnetic properties measurements, it was obviously found that B-site cation dilution resulted in a drastic decrease in the magnetization. Surprisingly large value of the coercive field was obtained for the undoped sample; H c=6198.8 Oe. Based on the mentioned results, one can recommend the use of such orthoferrite in magnetic recording media and as pining layer in spin valve for spintronic applications.
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