Non-spherical aluminum nanoparticles fabricated using picosecond laser ablation
来源期刊：International Journal of Minerals Metallurgy and Materials2020年第7期
论文作者：A.Brahma Swamulu S.Venugopal Rao G.Krishna Podagatlapalli
文章页码：980 - 986
摘 要：We report the picosecond laser ablation of aluminum targets immersed in a polar organic liquid（chloroform, CHCl3） with ～2 ps laser pulses at an input energy of ～350 μJ. The synthesized aluminum nanoparticles exhibited a surface plasmon resonance peak at ～340 nm.Scanning electron microscopy images of Al nanoparticles demonstrated the spherical morphology with an average size of（27 ± 3.6） nm. The formation of smaller spherical Al nanoparticles and the diminished growth could be from the formation of electric double layers on the Al nanoparticles. In addition to spherical aluminum nanoparticles, triangular/pentagonal/hexagonal nanoparticles were also observed in the colloidal solution. Field emission scanning electron microscopy images of ablated Al targets demonstrated laser induced periodic surface structures（LIPSSs）, which were the high spatial frequency LIPSSs（HSF-LIPSSs） since their grating period was ～280 nm. Additionally, coarse structures with a period of ～700 nm were observed.
A.Brahma Swamulu1,2，S.Venugopal Rao3，G.Krishna Podagatlapalli2
2. Department of Electronics & Physics, Gandhi Institute of Technology and Management Institute of Science, Gandhi Institute of Technology and Management deemed to be University3. Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad
摘 要：We report the picosecond laser ablation of aluminum targets immersed in a polar organic liquid（chloroform, CHCl3） with ～2 ps laser pulses at an input energy of ～350 μJ. The synthesized aluminum nanoparticles exhibited a surface plasmon resonance peak at ～340 nm.Scanning electron microscopy images of Al nanoparticles demonstrated the spherical morphology with an average size of（27 ± 3.6） nm. The formation of smaller spherical Al nanoparticles and the diminished growth could be from the formation of electric double layers on the Al nanoparticles. In addition to spherical aluminum nanoparticles, triangular/pentagonal/hexagonal nanoparticles were also observed in the colloidal solution. Field emission scanning electron microscopy images of ablated Al targets demonstrated laser induced periodic surface structures（LIPSSs）, which were the high spatial frequency LIPSSs（HSF-LIPSSs） since their grating period was ～280 nm. Additionally, coarse structures with a period of ～700 nm were observed.
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