Al替代Fe对<110>取向Tb-Dy-Fe合金显微组织、磁致伸缩性能和力学性能的影响
来源期刊:中国有色金属学报2012年第11期
论文作者:胡勇 丁雨田 王晓莉 李晓诚 王国斌
文章页码:3066 - 3073
关键词:Tb-Dy-Fe合金;显微组织;磁致伸缩;力学性能
Key words:Tb-Dy-Fe alloy; microstructure; magnetostriction; mechanical property
摘 要:采用区熔定向凝固方法制备<110>取向的Tb0.3Dy0.7(Fe1-xAlx)2(x=0,0.05,0.10,0.15)超磁致伸缩合金,研究不同含量Al原子替代Fe原子对于合金微观组织、磁致伸缩性能和力学性能的影响。结果表明:Al原子替代不改变定向凝固样品形成的<110>轴向择优取向,合金依然保持MgCu2型立方Laves相和部分稀土相结构。随着Al含量的增加,黑色RE(FeAl)2相和白色富稀土RE(Al)相的析出数量、尺寸及分布发生变化。微量Al原子(x≤0.05)替代可以显著提高材料低磁场下的动态响应及饱和磁致伸缩系数,随着Al含量进一步提高,合金系饱和磁致伸缩系数降低。Tb0.3Dy0.7(Fe1-xAlx)2(x=0,0.05,0.10,0.15)合金的压缩强度随着Al原子含量增加而增加,合金发生解理断 裂。当Al替代量x≤0.1时,合金具有良好的综合性能。
Abstract: The <110> oriented Tb0.3Dy0.7(Fe1-xAlx)2(x=0, 0.05, 0.10, 0.15) alloy was prepared by the method of zone-melting directional solidification. The effects of substituting Al for Fe on the microstructure, magnetostriction and mechanical properties were systemically investigated. The results show that the primary phase of Tb0.3Dy0.7(Fe1-xAlx)2 alloy were MgCu2-type cubic Laves phase structure and some RE phase, and the Al substitution doesn’t change the axial preferred orientation. With the increase of Al content, there are some RE(FeAl)2 phase and RE(Al) phase precipitated from the REFe2 matrix, and the quantity, size and distribution of the second phase vary with Al content increasing. The magnetization and magnetostriction measurements show that a small amount of Al substitution (x≤0.05) is beneficial to a decrease in the magneto crystalline anisotropy, and the saturation magnetostriction and dynamic response in low magnetic field increase drastically. With the increase of Al content, the saturation magnetostriction decreases distinctly, while the compressive strength increases. The fracture of the Tb0.3Dy0.7(Fe1-xAlx)2 alloy is cleavage fracture. The alloy with Al substitution range from 0 to 0.1 has optimal performances.
胡 勇1, 2,丁雨田1, 2,王晓莉1,李晓诚1,王国斌1
(1. 兰州理工大学 甘肃省有色金属新材料重点实验室,兰州 730050;
2. 兰州理工大学 温州泵阀工程研究院,温州 325105)
摘 要:采用区熔定向凝固方法制备<110>取向的Tb0.3Dy0.7(Fe1-xAlx)2(x=0,0.05,0.10,0.15)超磁致伸缩合金,研究不同含量Al原子替代Fe原子对于合金微观组织、磁致伸缩性能和力学性能的影响。结果表明:Al原子替代不改变定向凝固样品形成的<110>轴向择优取向,合金依然保持MgCu2型立方Laves相和部分稀土相结构。随着Al含量的增加,黑色RE(FeAl)2相和白色富稀土RE(Al)相的析出数量、尺寸及分布发生变化。微量Al原子(x≤0.05)替代可以显著提高材料低磁场下的动态响应及饱和磁致伸缩系数,随着Al含量进一步提高,合金系饱和磁致伸缩系数降低。Tb0.3Dy0.7(Fe1-xAlx)2(x=0,0.05,0.10,0.15)合金的压缩强度随着Al原子含量增加而增加,合金发生解理断 裂。当Al替代量x≤0.1时,合金具有良好的综合性能。
关键词:Tb-Dy-Fe合金;显微组织;磁致伸缩;力学性能
HU Yong1, 2, DING Yu-tian1, 2, WANG Xiao-li1, LI Xiao-cheng1, WANG Guo-bin1
(1. State Key Laboratory of Gansu Advanced Nonferrous Materials,
Lanzhou University of Technology, Lanzhou 730050, China;
2. Wenzhou Pump & Value Engineering Research Institute, L)
Abstract:The <110> oriented Tb0.3Dy0.7(Fe1-xAlx)2(x=0, 0.05, 0.10, 0.15) alloy was prepared by the method of zone-melting directional solidification. The effects of substituting Al for Fe on the microstructure, magnetostriction and mechanical properties were systemically investigated. The results show that the primary phase of Tb0.3Dy0.7(Fe1-xAlx)2 alloy were MgCu2-type cubic Laves phase structure and some RE phase, and the Al substitution doesn’t change the axial preferred orientation. With the increase of Al content, there are some RE(FeAl)2 phase and RE(Al) phase precipitated from the REFe2 matrix, and the quantity, size and distribution of the second phase vary with Al content increasing. The magnetization and magnetostriction measurements show that a small amount of Al substitution (x≤0.05) is beneficial to a decrease in the magneto crystalline anisotropy, and the saturation magnetostriction and dynamic response in low magnetic field increase drastically. With the increase of Al content, the saturation magnetostriction decreases distinctly, while the compressive strength increases. The fracture of the Tb0.3Dy0.7(Fe1-xAlx)2 alloy is cleavage fracture. The alloy with Al substitution range from 0 to 0.1 has optimal performances.
Key words:Tb-Dy-Fe alloy; microstructure; magnetostriction; mechanical property