Cu(Ⅱ) Complex/Multiwall Carbon Nanotube Modified Electrode for the Determination of Ascorbic Acid
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2015年第2期
论文作者：李小雨 李曦 XIONG Yan LIU Xin DONG Yulin LIU Peng
文章页码：412 - 415
摘 要：A sensitive and selective method for the determination of ascorbic acid（AA） using [Cu（phen）2]2+/multiwalled carbon nanotubes modified glassy carbon electrode was developed. Electrochemical behavior and surface characteristics of the modified electrode were studied using scanning electrode microscopy（SEM）, electrochemical impedance spectroscopy（EIS） and cyclic voltammetry（CV）. The experimental results showed that the modified electrode enhanced the electrochemical response of AA and exhibited good analytical performance for AA determination from 10 to 1 042 ?mol/L with a low detection limit of 9.67μmol/L（S/N=3）. The modified electrode was also applied to the determination of AA in the Vitamin tablets and showed good recovery.
李小雨，李曦，XIONG Yan，LIU Xin，DONG Yulin，LIU Peng
Department of Chemistry, School of Science, Wuhan University of Technology
摘 要：A sensitive and selective method for the determination of ascorbic acid（AA） using [Cu（phen）2]2+/multiwalled carbon nanotubes modified glassy carbon electrode was developed. Electrochemical behavior and surface characteristics of the modified electrode were studied using scanning electrode microscopy（SEM）, electrochemical impedance spectroscopy（EIS） and cyclic voltammetry（CV）. The experimental results showed that the modified electrode enhanced the electrochemical response of AA and exhibited good analytical performance for AA determination from 10 to 1 042 ?mol/L with a low detection limit of 9.67μmol/L（S/N=3）. The modified electrode was also applied to the determination of AA in the Vitamin tablets and showed good recovery.
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