Crystal structure and magnetic properties of YbZn0.7In1.3
来源期刊:JOURNAL OF RARE EARTHS2011年第10期
论文作者:Yu.Verbovytskyy L.C.J.Pereira A.P.Gon alves
文章页码:943 - 945
摘 要:The new ternary YbZn0.7In1.3 compound was synthesized in evacuated quartz ampoules at 900 ℃,followed by annealing at 400 ℃.It crystallized in the UHg2 structure type with a=0.47934(5) nm,c=0.36955(5) nm,V=0.073535(15) nm3.The shortest distances between theatoms in this structure were equal to 0.3696 nm(Yb-Yb),0.3328 nm(Yb-M) and 0.2767 nm(M-M),respectively.Magnetization measurements indicated that the title compound exhibited a paramagnetic behavior down to 2 K,with antiferromagnetic-like interactions.Calculatedmagnetic moment for YbZn0.7In1.3(μeff =3.86 μB/Yb) could indicate mixed valence state of Yb.
Yu.Verbovytskyy,L.C.J.Pereira,A.P.Gon alves
摘 要:The new ternary YbZn0.7In1.3 compound was synthesized in evacuated quartz ampoules at 900 ℃,followed by annealing at 400 ℃.It crystallized in the UHg2 structure type with a=0.47934(5) nm,c=0.36955(5) nm,V=0.073535(15) nm3.The shortest distances between theatoms in this structure were equal to 0.3696 nm(Yb-Yb),0.3328 nm(Yb-M) and 0.2767 nm(M-M),respectively.Magnetization measurements indicated that the title compound exhibited a paramagnetic behavior down to 2 K,with antiferromagnetic-like interactions.Calculatedmagnetic moment for YbZn0.7In1.3(μeff =3.86 μB/Yb) could indicate mixed valence state of Yb.
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