Effect of acidic surface functional groups on Cr(Ⅵ) removal by activated carbon from aqueous solution
来源期刊：Rare Metals2010年第3期
论文作者：ZHOU Hualeia and CHEN Yunfab a School of Applied Sciences,University of Science and Technology Beijing,Beijing ,China b State Key Laboratory of Multi-phase Complex System,Institute of Process Engineering,Chinese Academy of Sciences,Beijing ,China
文章页码：333 - 338
摘 要：The activated carbon with high surface area was prepared by KOH activation.It was further modified by H2SO4 and HNO3 to introduce more surface functional groups.The pore structure of the activated carbons before and after modification was analyzed based on the nitrogen adsorption isotherms.The morphology of those activated carbons was characterized using scanning electronic microscopy (SEM).The surface functional groups were determined by Fourier transform infrared spectroscopy (FTIR).The quantity of those groups was measured by the Boehm titration method.Cr(VI) removal by the activated carbons from aqueous solution was investigated at different pH values.The results show that compared with H2SO4,HNO3 destructs the original pore of the activated carbon more seriously and induces more acidic surface functional groups on the activated carbon.The pH value of the solution plays a key role in the Cr(VI) removal.The ability of reducing Cr(VI) to Cr(III) by the activated carbons is relative to the acidic surface functional groups.At higher pH values,the Cr(VI) removal ratio is improved by increasing the acidic surface functional groups of the activated carbons.At lower pH values,however,the acidic surface functional groups almost have no effect on the Cr(VI) removal by the activated carbon from aqueous solution.
ZHOU Hualeia and CHEN Yunfab a School of Applied Sciences,University of Science and Technology Beijing,Beijing 100083,China b State Key Laboratory of Multi-phase Complex System,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China
摘 要：The activated carbon with high surface area was prepared by KOH activation.It was further modified by H2SO4 and HNO3 to introduce more surface functional groups.The pore structure of the activated carbons before and after modification was analyzed based on the nitrogen adsorption isotherms.The morphology of those activated carbons was characterized using scanning electronic microscopy (SEM).The surface functional groups were determined by Fourier transform infrared spectroscopy (FTIR).The quantity of those groups was measured by the Boehm titration method.Cr(VI) removal by the activated carbons from aqueous solution was investigated at different pH values.The results show that compared with H2SO4,HNO3 destructs the original pore of the activated carbon more seriously and induces more acidic surface functional groups on the activated carbon.The pH value of the solution plays a key role in the Cr(VI) removal.The ability of reducing Cr(VI) to Cr(III) by the activated carbons is relative to the acidic surface functional groups.At higher pH values,the Cr(VI) removal ratio is improved by increasing the acidic surface functional groups of the activated carbons.At lower pH values,however,the acidic surface functional groups almost have no effect on the Cr(VI) removal by the activated carbon from aqueous solution.
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