A Comparative Study of Tribological Properties between Perfluoro and Non-perfluoro Alkylsilane Self-assembled Monolayers（SAMs）
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2009年第4期
论文作者：王新宽 刘宇宏
文章页码：588 - 593
摘 要：The tribological properties of perfluoro and non-perfluoro alkylsilane molecular films were investigated and compared detailedly. Their surface properties were characterized by X-ray photoelectron spectroscopy （XPS）, atomic force microscopy （AFM） and contact angle （CA） measurement. A ball-on-disk tribometer was used to study the frictional properties of these alkylsilane monolayers. The experimental results reveal that the alkylsilane molecular films are good candidates to decrease friction and they have good capability to endure rigorous shear forces. Perfluoro alkylsilane molecular films are bonded better with the Si substrate than the simple hydrocarbon ones. The effects of sliding velocity and normal load on friction coefficient are evident and the friction coefficient increases with the increase of the sliding velocity. However, friction coefficient decreases with the increase of normal load initially and then increases, indicating there exists a critical normal load for the load effect.
王新宽，刘宇宏
State Key Laboratory of Tribology,Tsinghua University
摘 要：The tribological properties of perfluoro and non-perfluoro alkylsilane molecular films were investigated and compared detailedly. Their surface properties were characterized by X-ray photoelectron spectroscopy （XPS）, atomic force microscopy （AFM） and contact angle （CA） measurement. A ball-on-disk tribometer was used to study the frictional properties of these alkylsilane monolayers. The experimental results reveal that the alkylsilane molecular films are good candidates to decrease friction and they have good capability to endure rigorous shear forces. Perfluoro alkylsilane molecular films are bonded better with the Si substrate than the simple hydrocarbon ones. The effects of sliding velocity and normal load on friction coefficient are evident and the friction coefficient increases with the increase of the sliding velocity. However, friction coefficient decreases with the increase of normal load initially and then increases, indicating there exists a critical normal load for the load effect.
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