Magnetic properties of melt-spun ribbons(Sm1-xZrx)(Fe0.92Ti0.08)10 with ThMn12 structure and their hydrides
来源期刊:JOURNAL OF RARE EARTHS2019年第10期
论文作者:A.G.Popov A.V.Protasov V.S.Gaviko D.A.Kolodkin P.B.Terentev E.G.Gerasimov Tianli Zhang Chengbao Jiang
文章页码:1066 - 1071
摘 要:The structure and magnetic hysteresis properties of the cast Sm1-xZrx(Fe0.92Ti0.08)10(x = 0-0.3)alloys and melt-spun ribbons prepared from them were studied.In the cast alloy with x>0.2, a considerable amount of the eutectic phase is found in the SEM micrographs.Analysis of the temperature dependences of the magnetic susceptibility and XRD patterns allows amorphous state in the as-spun ribbons with x>0.2 to be determined.The specific magnetization measured in a field of 17 kOe and remanence decrease with increasing annealing temperature from 800 to 900 ℃ and weakly depend on Zr concentration.The maximal value of coercivity Hc = 4.7 kOe is obtained on the ribbons with x = 0.2 after annealing at 850℃ for 10 min.After additional hydrogenation of the ribbons,both the coercivity and remanence increase by 54% and 7%,respectively.
A.G.Popov1,2,A.V.Protasov1,2,V.S.Gaviko1,2,D.A.Kolodkin1,P.B.Terentev3,4,E.G.Gerasimov3,4,Tianli Zhang5,Chengbao Jiang5
1. M.N.Miheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences2. Institute of Natural Sciences and Mathematics, Ural Federal University3. M.N.Miheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences,Str.S.Kovalevskoy4. Institute of Natural Sciences and Mathematics, Ural Federal University,pr.Mira5. School of Materials Science and Engineering, Beihang University
摘 要:The structure and magnetic hysteresis properties of the cast Sm1-xZrx(Fe0.92Ti0.08)10(x = 0-0.3)alloys and melt-spun ribbons prepared from them were studied.In the cast alloy with x>0.2, a considerable amount of the eutectic phase is found in the SEM micrographs.Analysis of the temperature dependences of the magnetic susceptibility and XRD patterns allows amorphous state in the as-spun ribbons with x>0.2 to be determined.The specific magnetization measured in a field of 17 kOe and remanence decrease with increasing annealing temperature from 800 to 900 ℃ and weakly depend on Zr concentration.The maximal value of coercivity Hc = 4.7 kOe is obtained on the ribbons with x = 0.2 after annealing at 850℃ for 10 min.After additional hydrogenation of the ribbons,both the coercivity and remanence increase by 54% and 7%,respectively.
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