Adsorption of rare earth ions using carbonized polydopamine nano carbon shells
来源期刊:JOURNAL OF RARE EARTHS2016年第1期
论文作者:孙晓琦 LUO Huimin Shannon M.Mahurin LIU Rui HOU Xisen DAI Sheng
文章页码:77 - 82
摘 要:Herein we reported the structure effects of carbon nano-shells prepared by the carbonization of polydopamine for the adsorption of rare earth elements(REEs) for the first time. Solid carbon spheres, 60 nm carbon shells and 500 nm carbon shells were prepared and evaluated for adsorption and desorption of REEs. The adsorption performance of carbon nano-shells for REEs was far superior to the solid carbon spheres. In addition, the effect of acidity on the adsorption and desorption properties was discussed. The good adsorption performance of the carbon nano-shells could be attributed to their pore structure, specific surface area, and the presence of both amine and carbonyl groups from the grafted dopamine.
孙晓琦1,2,LUO Huimin3,Shannon M.Mahurin1,LIU Rui1,HOU Xisen1,DAI Sheng1,4
1. Chemical Sciences Division Oak Ridge National Laboratory2. Xiamen Institute of Rare Earth Materials Haixi Institute Chinese Academy of Sciences3. Energy and Transportation Science Division Oak Ridge National Laboratory4. Department of Chemistry University of Tennessee
摘 要:Herein we reported the structure effects of carbon nano-shells prepared by the carbonization of polydopamine for the adsorption of rare earth elements(REEs) for the first time. Solid carbon spheres, 60 nm carbon shells and 500 nm carbon shells were prepared and evaluated for adsorption and desorption of REEs. The adsorption performance of carbon nano-shells for REEs was far superior to the solid carbon spheres. In addition, the effect of acidity on the adsorption and desorption properties was discussed. The good adsorption performance of the carbon nano-shells could be attributed to their pore structure, specific surface area, and the presence of both amine and carbonyl groups from the grafted dopamine.
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