Thermoelectric Properties of Ca3Co4O9 Ceramics
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2010年第2期
论文作者：漆小玲 曾令可
文章页码：287 - 290
摘 要：Ca3Co4O9 ceramics were prepared using the sol-gel process with ordinary pressing sintering and their thermoelectric properties were measured from room temperature to 673 K. The experimental results show that single phase Ca3Co4O9 can be fabricated at 750-900 ℃ in different citrate acid molar proportions for 0.2-1.0. For all the oxides, both the Seebeck coefficients S and the electrical conductivitiesκincrease with the increasing temperature. The Seebeck coefficients S are all positive. The thermal conductivities κ increase with the increasing temperature also and the lattice thermal conductivityκl plays an important role to the thermal conductivity κ. The citrate acid molar proportions have a large influence on the particle sizes, which influences the thermoelectric properties of the ceramics. The figure of merit increases with the increasing temperature and reaches 4.5×10-5 K-1 at 573 K for the sample in the citrate acid molar proportion of 0.46.
漆小玲1,2，曾令可1
1. College of Materials Science and Engineering, South China University of Technology2. Educational Ministry’s Key Lab of Enhanced Heat Transfer and Energy Conservation, School of Chemistry and Chemical Engineering, South China University of Technology
摘 要：Ca3Co4O9 ceramics were prepared using the sol-gel process with ordinary pressing sintering and their thermoelectric properties were measured from room temperature to 673 K. The experimental results show that single phase Ca3Co4O9 can be fabricated at 750-900 ℃ in different citrate acid molar proportions for 0.2-1.0. For all the oxides, both the Seebeck coefficients S and the electrical conductivitiesκincrease with the increasing temperature. The Seebeck coefficients S are all positive. The thermal conductivities κ increase with the increasing temperature also and the lattice thermal conductivityκl plays an important role to the thermal conductivity κ. The citrate acid molar proportions have a large influence on the particle sizes, which influences the thermoelectric properties of the ceramics. The figure of merit increases with the increasing temperature and reaches 4.5×10-5 K-1 at 573 K for the sample in the citrate acid molar proportion of 0.46.
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